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Title: | MOF-aminoclay composites for superior CO2 capture, separation and enhanced catalytic activity in chemical fixation of CO2 |
Authors: | Chakraborty, Anindita Achari, Amritroop Eswaramoorthy, M. Maji, Tapas Kumar |
Keywords: | Chemistry Metal-Organic-Framework Porous Coordination Polymer Carbon-Dioxide Capture Adsorption-Kinetics Graphene Oxide Nanocomposites Fabrication Crystals Ch4 |
Issue Date: | 2016 |
Publisher: | Royal Society of Chemistry |
Citation: | Chakraborty, A.; Bhattacharyya, S.; Hazra, A.; Ghosh, A. C.; Maji, T. K., Post-synthetic metalation in an anionic MOF for efficient catalytic activity and removal of heavy metal ions from aqueous solution. Chemical Communications 2016, 52 (13), 2831-2834 http://dx.doi.org/10.1039/c5cc09814a Chemical Communications 52 76 |
Abstract: | We delineate the growth and stabilization of ultra-small (2-3 nm) {Cu-3(BTC)(2)(H2O)(2)center dot xH(2)O} MOF nanoparticles on a 2D layered aminoclay template. The composite shows significant CO2 uptake (5.35 mmol g(-1) at 298 K, 1 bar; 46% higher than pristine bulk MOF), superior CO2 separation efficiency from CO2/N-2 and CO2/CH4 mixtures and higher catalytic proficiency for chemical fixation of CO2 into cyclic carbonates. |
Description: | Restricted Access |
URI: | https://libjncir.jncasr.ac.in/xmlui/10572/2124 |
ISSN: | 1359-7345 |
Appears in Collections: | Research Articles (Eswaramoorthy M.) |
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