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Please use this identifier to cite or link to this item: https://libjncir.jncasr.ac.in/xmlui/handle/10572/2412
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dc.contributor.authorDonakowski, Martin D.
dc.contributor.authorLu, Hongcheng
dc.contributor.authorGautier, Romain
dc.contributor.authorSaha, Rana
dc.contributor.authorSundaresan, A.
dc.contributor.authorPoeppelmeier, Kenneth R.
dc.date.accessioned2017-02-21T07:00:52Z-
dc.date.available2017-02-21T07:00:52Z-
dc.date.issued2014
dc.identifier.citationDonakowski, MD; Lu, HC; Gautier, R; Saha, R; Sundaresan, A; Poeppelmeier, KR, Synthesis and Magnetic Properties of beta-KVOF3. Zeitschrift Fur Anorganische Und Allgemeine Chemie 2014, 640 (6) 1109-1114, http://dx.doi.org/10.1002/zaac.201300576en_US
dc.identifier.citationZeitschrift Fur Anorganische Und Allgemeine Chemieen_US
dc.identifier.citation640en_US
dc.identifier.citation6en_US
dc.identifier.issn0044-2313
dc.identifier.urihttps://libjncir.jncasr.ac.in/xmlui/10572/2412-
dc.descriptionRestricted Accessen_US
dc.description.abstractThe potassium vanadium oxide-fluoride phase -KVOF3 was prepared by in-situ reduction with hydrothermal methods and characterized by single-crystal X-ray diffraction and magnetic susceptibility measurements. The compound is orthorhombic [space group Pnma, a = 7.1596(2) angstrom, b = 7.5392(2) angstrom, c = 13.0506(4) angstrom, Z = 8]. The material is structurally similar and isoformulaic to d(1) materials of formulae AVOF(3) (A(+) = alkali metal, ammonium, or organic cation). Magnetic susceptibility data were successfully fit with a Heisenberg chain model. In-situ reduction of V5+ to V4+ during the hydrothermal reaction conditions was observed in the presence of Br- anions. The role of bromide ions in this reduction is explained and employed to reduce a d(0) vanadium species to obtain a material with magnetic behavior.en_US
dc.description.uri1521-3749en_US
dc.description.urihttp://dx.doi.org/10.1002/zaac.201300576en_US
dc.language.isoEnglishen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.rights@Wiley-V C H Verlag Gmbh, 2014en_US
dc.subjectInorganic & Nuclear Chemistryen_US
dc.subjectHeisenberg Chainen_US
dc.subjectVanadiumen_US
dc.subjectOxide-Fluorideen_US
dc.subjectHydrothermal Synthesisen_US
dc.subjectCrystal-Structureen_US
dc.subjectOxide-Fluorideen_US
dc.subjectVanadium(Iv) Oxyfluoridesen_US
dc.subjectTransition-Metalsen_US
dc.subjectComposition Spaceen_US
dc.subjectAnionen_US
dc.subjectTemperatureen_US
dc.subjectSystemen_US
dc.subjectSpinen_US
dc.titleSynthesis and Magnetic Properties of beta-KVOF3en_US
dc.typeArticleen_US
Appears in Collections:Research Articles (Sundaresan A.)

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