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Open-Framework Rubidium Halides Incorporated in Cadmium Oxalate Host Lattices
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| dc.contributor.author | Vaidhyanathan, R
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| dc.contributor.author | Natarajan, Srinivasan
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| dc.contributor.author | Rao, C N R
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| dc.date.accessioned | 2012-11-22T11:25:02Z | |
| dc.date.available | 2012-11-22T11:25:02Z | |
| dc.date.issued | 2002-08 | |
| dc.identifier | 0022-4596 | en_US |
| dc.identifier.citation | Journal of Solid State Chemistry 167(2), 274-281 (2002) | en_US |
| dc.identifier.uri | https://libjncir.jncasr.ac.in/xmlui/10572/1050 | |
| dc.description | Restricted Access | en_US |
| dc.description.abstract | The metathetic reaction between CdBr2 and rubidium oxalate under hydrothermal conditions yields [RbBr] [Cd6(C2O4)(6)]. 2H(2)O, I, containing Cd6O24 clusters with the Br- ions in the center. The RbBr moiety forms a three-dimensional Fm3m structure, but with a unit cell double that of the normal stable phase. The hydrothermal reaction between rubidium oxalate and CdCl2 in the presence of NO3- ions gives [Rb2Cd(NO3)(Cl) (C2O4)(H2O)], II, containing cadmium chloro-oxalate layers. The Rb+ ions present between the layers interact with the Cl atoms to form a one-dimensional RbCl chain decorated by NOT groups. (C) 2002 Elsevier Science (USA). | en_US |
| dc.description.uri | http://dx.doi.org/10.1006/jssc.2002.9530 | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Academic Press Inc Elsevier Science | en_US |
| dc.rights | © 2002 Elsevier Science | en_US |
| dc.subject | Directing Organic Amines | en_US |
| dc.subject | Crystal-Structure | en_US |
| dc.subject | Mil-N | en_US |
| dc.subject | Cobalt(Ii) Carboxylate | en_US |
| dc.subject | Phosphates | en_US |
| dc.subject | Temperature | en_US |
| dc.title | Open-Framework Rubidium Halides Incorporated in Cadmium Oxalate Host Lattices | en_US |
| dc.type | Article | en_US |
