Amine-templated metal squarates

Dan, Meenakshi; Sivashankar, K; Cheetham, A K; Rao, C N R

dc.contributor.author	Dan, Meenakshi
dc.contributor.author	Sivashankar, K
dc.contributor.author	Cheetham, A K
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-11-23T08:59:33Z
dc.date.available	2012-11-23T08:59:33Z
dc.date.issued	2003-08
dc.identifier	0022-4596	en_US
dc.identifier.citation	Journal of Solid State Chemistry 174(1), 60-68 (2003)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/1053
dc.description	Restricted Access	en_US
dc.description.abstract	Two layered amine-templated cobalt squarates, [C6N2H14](2)[Co-2(C4O4)(3)(H2O)(4)], I, and [C3N2H5](2)[CO2(C4O4)(3)(H2O)(4)], II, have been prepared under hydrothermal conditions. Both I and II contain chains formed by dimers comprising two cobalt atoms bound to the squarate units, the chains being connected through hydrogen bond interactions. An amine-templated cobalt squarate of the formula [C4N2H12][CO(C4O4)(2)(H2O)(4)][H2O](2), III, as well as its Ni, Zn and Cd analogues have been prepared by room temperature reactions. III has a layered architecture wherein the cobalt-squarate monomers are linked by the amine molecules. Co and Zn analogues of [Ni(C4O4)(H2O)(2)(C3N2H4)] with ligating imidazole units have also been prepared and characterized. (C) 2003 Elsevier Science (USA). All rights reserved.	en_US
dc.description.uri	http://dx.doi.org/10.1016/S0022-4596(03)00174-9	en_US
dc.language.iso	en	en_US
dc.publisher	Academic Press Inc Elsevier Science	en_US
dc.rights	© 2003 Elsevier Science	en_US
dc.subject	Organic Framework	en_US
dc.subject	Oxalates	en_US
dc.subject	Spectra	en_US
dc.subject	Crystal	en_US
dc.subject	Nickel	en_US
dc.subject	Ni	en_US
dc.title	Amine-templated metal squarates	en_US
dc.type	Article	en_US