dc.contributor.author |
Pasha, Intyaj
|
|
dc.contributor.author |
Choudhury, Amitava
|
|
dc.contributor.author |
Rao, C N R
|
|
dc.date.accessioned |
2012-11-23T09:08:02Z |
|
dc.date.available |
2012-11-23T09:08:02Z |
|
dc.date.issued |
2003-09 |
|
dc.identifier |
0022-4596 |
en_US |
dc.identifier.citation |
Journal of Solid State Chemistry 174(2), 386-391 (2003) |
en_US |
dc.identifier.uri |
https://libjncir.jncasr.ac.in/xmlui/10572/1054 |
|
dc.description |
Restricted Access |
en_US |
dc.description.abstract |
An organically templated cadmium selenate of the formula [enH(2)][Cd(H2O)(2)(SeO4)(2)] I has been synthesized by carrying out the reaction between CdO and H2SeO4 in the presence of the amine in aqueous medium at 80degreesC. The structure of I involves isolated infinite [Cd(H2O)(2)(SeO4)(2)](2-) chains running along the c-axis, with the protonated ethylenediamine molecules between them. Crystal data for I are as follows: Monoclinic, space group= C2/c, a = 10.5059(7), b = 10.3605(7), c = 10.6028(7)Å, β = 94.666(2)degrees, V = 1150.25(13) Å3, z = 8, R-1 = 0.0237, wR(2) = 0.0500 (for all data). (C) 2003 Elsevier Inc. All rights reserved. |
en_US |
dc.description.uri |
http://dx.doi.org/10.1016/S0022-4596(03)00256-1 |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Academic Press Inc Elsevier Science |
en_US |
dc.rights |
© 2003 Elsevier Inc |
en_US |
dc.subject |
cadmium selenate |
en_US |
dc.subject |
organically templated material |
en_US |
dc.subject |
one-dimensional structure |
en_US |
dc.subject |
Krohnkite-type chain and thermogravimetric analysis |
en_US |
dc.subject |
Sulfates |
en_US |
dc.subject |
Phosphates |
en_US |
dc.subject |
Selenites |
en_US |
dc.title |
The first organically templated linear metal selenate |
en_US |
dc.type |
Article |
en_US |