A chiral mixed carboxylate, [Nd4(H2O)(2)(OOC(CH2)(3)COO)(4)(C2O4)(2)], exhibiting NLO properties

Vaidhyanathan, R; Natarajan, Srinivasan; Rao, C N R

dc.contributor.author	Vaidhyanathan, R
dc.contributor.author	Natarajan, Srinivasan
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-11-27T06:11:47Z
dc.date.available	2012-11-27T06:11:47Z
dc.date.issued	2004-04
dc.identifier	0022-4596	en_US
dc.identifier.citation	Journal of Solid State Chemistry 177(4-5), 1444-1448 (2004)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/1080
dc.description	Restricted Access	en_US
dc.description.abstract	Reaction of a mixture of neodymium carbonate, HCl, oxamic acid and glutaric acid under hydrothermal conditions gives rise to a new mixed carboxylate of neodymium, [Nd-4(H2O)(2)(OOC(CH2)(3)COO)(4)(C2O4)(2)], I. The structure, determined using single crystal X-ray diffraction, comprises a helical column formed by the grafting of the oxalate unit on to helical NdO9 chains, cross-linked by the glutarate anions. It is noteworthy that the pitch of the helix is equivalent to the length of the oxalate unit. Furthermore, I shows about 1.1 times the SHG activity of urea. (C) 2003 Elsevier Inc. All rights reserved.	en_US
dc.description.uri	http://dx.doi.org/10.1016/j.jssc.2003.11.026	en_US
dc.language.iso	en	en_US
dc.publisher	Academic Press Inc Elsevier Science	en_US
dc.rights	© 2004 Elsevier Inc	en_US
dc.subject	hydrothermal	en_US
dc.subject	mixed carboxylate	en_US
dc.subject	SHG	en_US
dc.subject	Nd	en_US
dc.subject	Zeolite-Beta	en_US
dc.subject	Structural-Characterization	en_US
dc.subject	Framework Topology	en_US
dc.subject	Phosphate	en_US
dc.subject	Channels	en_US
dc.subject	Urea	en_US
dc.title	A chiral mixed carboxylate, [Nd4(H2O)(2)(OOC(CH2)(3)COO)(4)(C2O4)(2)], exhibiting NLO properties	en_US
dc.type	Article	en_US