Abstract:
Photophysical properties of the singlet and triplet states of the fullerenes, C60 and C70, have been investigated in toluene, benzene, hexane and ethanol solutions by pico- and nano-second laser flash photolysis techniques. Lifetimes, extinction coefficients. quantum efficiencies of the formation of the excited states and such properties have been determined. True triplet-triplet absorption spectra of C60 and C70 are reported. C60, unlike C70, is found to undergo photoionization in ethanol solution giving solvated electrons.