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A calorimetric investigation of the assembly of gold nanorods to form necklaces

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dc.contributor.author Varghese, Neenu
dc.contributor.author Vivekchand, S R C
dc.contributor.author Govindaraj, A
dc.contributor.author Rao, C N R
dc.date.accessioned 2011-05-20T06:51:03Z
dc.date.available 2011-05-20T06:51:03Z
dc.date.issued 2008-01-04
dc.identifier 0009-2614 en_US
dc.identifier.citation Chemical Physics Letters 450(4-6), 340-344 (2008) en_US
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/120
dc.description Restricted access en_US
dc.description.abstract Interaction of gold nanorods with cysteine as well as 3-mercaptopropionic acid (MPA) has been investigated by isothermal titration calorimetry (ITC), in combination with electronic absorption spectroscopy and electron microscopy. The assembly process with MPA shows two steps, the first due to the binding of MPA to gold nanorods through the sulfur atom, and the second due to assembly of the MPA capped gold nanorods through the formation of cyclic hydrogen bonded dimers between the MPA molecules. In the case of cysteine only a single step is observed in ITC, due to the binding of the molecules to gold nanorods. (c) 2007 Elsevier B.V. All rights reserved. en_US
dc.description.uri http://dx.doi.org/10.1016/j.cplett.2007.11.022 en_US
dc.language.iso en en_US
dc.publisher Elsevier Science BV en_US
dc.rights © 2008 Elsevier Science BV en_US
dc.subject Isothermal Titration Calorimetry en_US
dc.subject Nanoparticles en_US
dc.subject Nanocrystals en_US
dc.title A calorimetric investigation of the assembly of gold nanorods to form necklaces en_US
dc.type Article en_US


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