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Hybrid structures formed by homo- and hetero leptic aliphatic dicarboxylates of lead with 2D-inorganic connectivity

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dc.contributor.author Thirumurugan, A
dc.contributor.author Rao, C N R
dc.date.accessioned 2012-12-05T12:43:22Z
dc.date.available 2012-12-05T12:43:22Z
dc.date.issued 2008-05
dc.identifier 0022-4596 en_US
dc.identifier.citation Journal of Solid State Chemistry 181(5), 1184-1194 (2008) en_US
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/1226
dc.description Restricted Access en_US
dc.description.abstract Three-dimensional homoleptic (single type of ligand) lead dicarboxylates with hybrid structures involving Pb–O–Pb linkages of the compositions, Pb(C5H6O4), I, and Pb(C6H8O4), II and III, have been synthesized and characterized. Three-dimensional heteroleptic (mixed ligands) lead dicarboxylates of the formulae, Pb2(C2O4)(C4H4O4), IV and Pb2(C2O4)(C6H8O4), V, with hybrid structures involving Pb–O–Pb linkages have also been prepared and characterized along with a novel two-dimensional lead nitrate-oxalate of the composition, (OPb2)2(C2O4)(NO3)2, VI. In all these dicarboxylates, there is two-dimensional inorganic connectivity and the lead (II) cation has hemi- or holo-directed coordination geometry. Depending upon the torsional angle and the coordination mode of the dicarboxylate anions as well as the geometry of the lead (II) cations, these hybrid compounds exhibit two types of two-dimensional inorganic connectivities. en_US
dc.description.uri http://dx.doi.org/10.1016/j.jssc.2008.02.021 en_US
dc.language.iso en en_US
dc.publisher Elsevier Inc en_US
dc.rights © 2008 Elsevier Inc en_US
dc.subject Inorganic–organic hybrid frameworks en_US
dc.subject Aliphatic dicarboxylates en_US
dc.subject Mixed ligands en_US
dc.subject Nitrate en_US
dc.subject Lead en_US
dc.title Hybrid structures formed by homo- and hetero leptic aliphatic dicarboxylates of lead with 2D-inorganic connectivity en_US
dc.type Article en_US


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