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Phase behaviour of supercooled liquid silicon

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dc.contributor.advisor Sastry, Srikanth en_US
dc.contributor.author Vasisht, Vishwas V.
dc.date.accessioned 2014-09-22T04:09:38Z
dc.date.available 2014-09-22T04:09:38Z
dc.date.issued 2013-03
dc.date.issued 2013 en_US
dc.identifier.citation Vasisht, Vishwas V. 2013, Phase behaviour of supercooled liquid silicon, Ph.D thesis, Jawaharlal Nehru Centre for Advanced Scientific Research, Bengaluru en_US
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/handle/10572/1407
dc.description Open Access en_US
dc.description.abstract Silicon, the second most abundant element in the earth’s crust, is ubiquitous in the form of silica and silicates in the natural world. In the elemental form, it is an essential component of the semiconductor technology. It was first prepared in its amorphous form by J.J. Berzelius and later the crystalline form by H.E. Sainte-Claire Deville [185] in the 1800’s. The crystalline and amorphous solid are the two most familiar forms of silicon, which have been studied extensively. The crystalline form of silicon is a tetravalent semiconductor (as is the amorphous solid) and upon melting at 1687K at ambient pressure, transforms to a metallic liquid with higher coordination number, around 6. Liquid silicon is relatively less studied, given the elevated temperatures at which it exists. Nevertheless, it has been a subject of substantial experimental, theoretical and computational investigation, both at temperatures above the melting temperature, and in the supercooled and stretched (negative pressure) states. The investigations of the metastable liquid (see FIG. 1.1) have been motivated, as this thesis seeks to demonstrate, by fundamental questions regarding (i) the eventual fate of metastable liquids upon deep undercooling and stretching, (ii) the interest in the possibility of a novel transition between two distinct liquid forms in a class of “tetrahedral” liquids to which silicon belongs, and (iii) the role of the thermodynamics of metastable liquid states on the kinetics of phase transformations, particularly to the crystalline state.
dc.language.iso English en_US
dc.publisher Jawaharlal Nehru Centre for Advanced Scientific Research, Bengaluru en_US
dc.rights © 2013 JNCASR en_US
dc.subject Silicon liquid en_US
dc.subject Phase behaviour
dc.subject Supercooled
dc.title Phase behaviour of supercooled liquid silicon en_US
dc.type Thesis en_US
dc.type.qualificationname Ph.D. en_US
dc.publisher.department Theoretical Sciences Unit (TSU) en_US


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