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Browsing Research Articles (Sridhar Rajaram) by Author "Reddy, Golipalli Ramana"

Browsing Research Articles (Sridhar Rajaram) by Author "Reddy, Golipalli Ramana"

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  • Activation of Benzyl Aryl Carbonates: The Role of Cation-pi Interactions 
    Reddy, Golipalli Ramana; Avadhani, Anusha S.; Rajaram, Sridhar (American Chemical Society, 2016)
    Benzyl aryl carbonates can react with a nucleophile to yield an activated electrophile and an aryloxide anion. Previously, we had utilized this in the synthesis of alpha-nitro esters from nitroalkanes. To further understand ...
  • Unusual Reactivity of Nitronates with an Aryl Alkyl Carbonate: Synthesis of alpha-Amino Esters 
    Reddy, Golipalli Ramana; Mukherjee, Debopreeti; Chittoory, Arjun Kumar; Rajaram, Sridhar (American Chemical Society, 2014)
    The monoanions of nitroalkanes are ambident nucleophiles that react with carbonate electrophiles through the oxygen atom. Products arising from reactivity at the carbon atom will yield alpha-nitro esters, which are precursors ...

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