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Nanoparticles produced by laser ablation of HfS3 in liquid medium: Inorganic fullerene-like structures of Hf2S

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dc.contributor.author Nath, Manashi
dc.contributor.author Rao, C N R
dc.contributor.author Popovitz-Biro, Ronit
dc.contributor.author Albu-Yaron, Angi
dc.contributor.author Tenne, Reshef
dc.date.accessioned 2012-01-11T11:23:47Z
dc.date.available 2012-01-11T11:23:47Z
dc.date.issued 2004-06-01
dc.identifier 0897-4756 en_US
dc.identifier.citation Chemistry Of Materials 16(11), 2238-2243 (2004) en_US
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/165
dc.description Restricted Access en_US
dc.description.abstract Inorganic fullerene-like structures (IF) of the layered hafnium sulfide, Hf2S, have been synthesized by the laser ablation of HfS3 in tert-butyl disulfide medium. Apart from the Hf2S IFs exhibiting quasi-spherical as well as faceted nested-shell geometries, quasi-spherical nanoparticles of HfS were observed by this means. Whereas Hf2S has anti-NbS2 structure with S layers sandwiched between two Hf layers, HfS has the nonlayered WC-type structure. The nanoparticles of HfS show excess sulfur in the core, and they do not possess closed-shell geometry. The mechanism of formation of these nanoparticles has also been discussed en_US
dc.description.uri http://dx.doi.org/10.1021/cm035246s en_US
dc.language.iso en en_US
dc.publisher American Chemical Society en_US
dc.rights © 2004 American Chemical Society en_US
dc.subject Aqueous-Solution en_US
dc.subject Nanotubes en_US
dc.subject Nanocrystals en_US
dc.subject Irradiation en_US
dc.subject Interface en_US
dc.title Nanoparticles produced by laser ablation of HfS3 in liquid medium: Inorganic fullerene-like structures of Hf2S en_US
dc.type Article en_US


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