DSpace Repository

Shining light on clay-chromophore hybrids: layered templates for accelerated ring closure photo-oxidation

Show simple item record

dc.contributor.author Jain, Ankit
dc.contributor.author Achari, Amritroop
dc.contributor.author Mothi, Nivin
dc.contributor.author Eswaramoorthy, M.
dc.contributor.author George, Subi J.
dc.date.accessioned 2016-10-28T05:57:56Z
dc.date.available 2016-10-28T05:57:56Z
dc.date.issued 2015
dc.identifier.citation Chemical Science en_US
dc.identifier.citation 6 en_US
dc.identifier.citation 11 en_US
dc.identifier.citation Jain, A.; Achari, A.; Mothi, N.; Eswaramoorthy, M.; George, S. J., Shining light on clay-chromophore hybrids: layered templates for accelerated ring closure photo-oxidation. Chemical Science 2015, 6 (11), 6334-6340. en_US
dc.identifier.issn 2041-6520
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/1882
dc.description Restricted access en_US
dc.description.abstract Templates with specific microenvironments have been long employed to facilitate specialized reactions. From enzymes to metal organic frameworks (MOFs), various systems have exerted their prowess to affect specific chemical reactions. Here we report, for the first time, the acceleration of a ring closure photo-oxidation reaction due to the specific structural constraints provided by layered materials. A stilbene derivative has been used as a prototype reactant and the di-hydrophenanthrene intermediate has been isolated and characterized en route to the complete photo-oxidation. Combining the gathered evidence, a possible mechanism for the chemical transformation has been proposed. Kinetic analysis showed that layered materials help to manipulate the rate of the electrocyclic ring closure and, in turn, accelerate the complete reaction sequence. The structural microenvironment induced by layered materials could be a unique platform to probe and stabilize a plethora of photo-oxidative reactions and intermediates. en_US
dc.description.uri 2041-6539 en_US
dc.description.uri http://dx.doi.org/10.1039/c5sc02215k en_US
dc.language.iso English en_US
dc.publisher Royal Society of Chemistry en_US
dc.rights ?Royal Society of Chemistry, 2015 en_US
dc.subject Chemistry en_US
dc.subject Aggregation-Induced Emission en_US
dc.subject Metal-Organic Frameworks en_US
dc.subject Oxidative Cyclization en_US
dc.subject Coordination Polymers en_US
dc.subject Surface Topographies en_US
dc.subject Electron-Transfer en_US
dc.subject Building-Block en_US
dc.subject Photocyclization en_US
dc.subject Fluorescence en_US
dc.subject Photodimerization en_US
dc.title Shining light on clay-chromophore hybrids: layered templates for accelerated ring closure photo-oxidation en_US
dc.type Article en_US


Files in this item

This item appears in the following Collection(s)

Show simple item record

Search DSpace


Advanced Search

Browse

My Account