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P-C Bond Cleavage-Assisted Lanthanide Phosphate Coordination Polymers

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dc.contributor.author Goura, Joydeb
dc.contributor.author Walsh, James P. S.
dc.contributor.author Tuna, Floriana
dc.contributor.author Halder, Ritesh
dc.contributor.author Maji, Tapas Kumar
dc.contributor.author Chandrasekhar, Vadapalli
dc.date.accessioned 2016-12-22T11:26:56Z
dc.date.available 2016-12-22T11:26:56Z
dc.date.issued 2015
dc.identifier.citation Crystal Growth & Design en_US
dc.identifier.citation 15 en_US
dc.identifier.citation 6 en_US
dc.identifier.citation Goura, J.; Walsh, J. P. S.; Tuna, F.; Halder, R.; Maji, T. K.; Chandrasekhar, V., P-C Bond Cleavage-Assisted Lanthanide Phosphate Coordination Polymers. Crystal Growth & Design 2015, 15 (6), 2555-2560. en_US
dc.identifier.issn 1528-7483
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/1955
dc.description Restricted access en_US
dc.description.abstract The reaction of lanthanide(III) salts with an organodiphosphonic acid under hydrothermal conditions resulted in a P-C bond cleavage affording [{Eu-4(PO4)(PO4)(0.5)x(4)(PO4)(0.25x4)(H2O)(2)}center dot 6H(2)O](n) (1), [{Dy-4(PO4)center dot(PO4)(0.5x4)(PO4)(0.25x4)(H2O)(2)}center dot 6H(2)O](n) (2), and [{Gd(PO4)(0.5)(PO4)(0.5)(H2O)(3)}center dot 2H(2)O](n) (3). 1 and 2 are porous 3D coordination polymers whose repeating units possess a dimeric motif. While one lanthanide ion in the dimer is eight-coordinate in a distorted square-antiprismatic geometry, the other is nine-coordinate and present in a distorted monocapped square-antiprismatic geometry. In contrast to 1 and 2, 3 possesses a 2D architecture; the asymmetric unit contains a monomeric Gd-III center which is nine-coordinate in a distorted monocapped square-antiprismatic geometry. en_US
dc.description.uri 1528-7505 en_US
dc.description.uri http://dx.doi.org/10.1021/cg5017005 en_US
dc.language.iso English en_US
dc.publisher American Chemical Society en_US
dc.rights ?American Chemical Society, 2015 en_US
dc.subject Chemistry en_US
dc.subject Crystallography en_US
dc.subject Materials Science en_US
dc.subject Single-Molecule-Magnet en_US
dc.subject Metal-Organic-Framework en_US
dc.subject Pyrazole Ligands en_US
dc.subject Adsorption Properties en_US
dc.subject Crystal-Structure en_US
dc.subject Smm Behavior en_US
dc.subject Ion Magnet en_US
dc.subject Luminescent en_US
dc.subject Phosphonate en_US
dc.subject Complexes en_US
dc.title P-C Bond Cleavage-Assisted Lanthanide Phosphate Coordination Polymers en_US
dc.type Article en_US


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