dc.contributor.author |
Goura, Joydeb
|
|
dc.contributor.author |
Walsh, James P. S.
|
|
dc.contributor.author |
Tuna, Floriana
|
|
dc.contributor.author |
Halder, Ritesh
|
|
dc.contributor.author |
Maji, Tapas Kumar
|
|
dc.contributor.author |
Chandrasekhar, Vadapalli
|
|
dc.date.accessioned |
2016-12-22T11:26:56Z |
|
dc.date.available |
2016-12-22T11:26:56Z |
|
dc.date.issued |
2015 |
|
dc.identifier.citation |
Crystal Growth & Design |
en_US |
dc.identifier.citation |
15 |
en_US |
dc.identifier.citation |
6 |
en_US |
dc.identifier.citation |
Goura, J.; Walsh, J. P. S.; Tuna, F.; Halder, R.; Maji, T. K.; Chandrasekhar, V., P-C Bond Cleavage-Assisted Lanthanide Phosphate Coordination Polymers. Crystal Growth & Design 2015, 15 (6), 2555-2560. |
en_US |
dc.identifier.issn |
1528-7483 |
|
dc.identifier.uri |
https://libjncir.jncasr.ac.in/xmlui/10572/1955 |
|
dc.description |
Restricted access |
en_US |
dc.description.abstract |
The reaction of lanthanide(III) salts with an organodiphosphonic acid under hydrothermal conditions resulted in a P-C bond cleavage affording [{Eu-4(PO4)(PO4)(0.5)x(4)(PO4)(0.25x4)(H2O)(2)}center dot 6H(2)O](n) (1), [{Dy-4(PO4)center dot(PO4)(0.5x4)(PO4)(0.25x4)(H2O)(2)}center dot 6H(2)O](n) (2), and [{Gd(PO4)(0.5)(PO4)(0.5)(H2O)(3)}center dot 2H(2)O](n) (3). 1 and 2 are porous 3D coordination polymers whose repeating units possess a dimeric motif. While one lanthanide ion in the dimer is eight-coordinate in a distorted square-antiprismatic geometry, the other is nine-coordinate and present in a distorted monocapped square-antiprismatic geometry. In contrast to 1 and 2, 3 possesses a 2D architecture; the asymmetric unit contains a monomeric Gd-III center which is nine-coordinate in a distorted monocapped square-antiprismatic geometry. |
en_US |
dc.description.uri |
1528-7505 |
en_US |
dc.description.uri |
http://dx.doi.org/10.1021/cg5017005 |
en_US |
dc.language.iso |
English |
en_US |
dc.publisher |
American Chemical Society |
en_US |
dc.rights |
?American Chemical Society, 2015 |
en_US |
dc.subject |
Chemistry |
en_US |
dc.subject |
Crystallography |
en_US |
dc.subject |
Materials Science |
en_US |
dc.subject |
Single-Molecule-Magnet |
en_US |
dc.subject |
Metal-Organic-Framework |
en_US |
dc.subject |
Pyrazole Ligands |
en_US |
dc.subject |
Adsorption Properties |
en_US |
dc.subject |
Crystal-Structure |
en_US |
dc.subject |
Smm Behavior |
en_US |
dc.subject |
Ion Magnet |
en_US |
dc.subject |
Luminescent |
en_US |
dc.subject |
Phosphonate |
en_US |
dc.subject |
Complexes |
en_US |
dc.title |
P-C Bond Cleavage-Assisted Lanthanide Phosphate Coordination Polymers |
en_US |
dc.type |
Article |
en_US |