dc.contributor.author |
Naidu, B. S.
|
|
dc.contributor.author |
Gupta, Uttam
|
|
dc.contributor.author |
Maitra, Urmimala
|
|
dc.contributor.author |
Rao, C. N. R.
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|
dc.date.accessioned |
2017-02-21T06:56:22Z |
|
dc.date.available |
2017-02-21T06:56:22Z |
|
dc.date.issued |
2014 |
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dc.identifier.citation |
Naidu, BS; Gupta, U; Maitra, U; Rao, CNR, Visible light induced oxidation of water by rare earth manganites, cobaltites and related oxides. Chemical Physics Letters 2014, 591, 277-281, http://dx.doi.org/10.1016/j.cplett.2013.10.089 |
en_US |
dc.identifier.citation |
Chemical Physics Letters |
en_US |
dc.identifier.citation |
591 |
en_US |
dc.identifier.issn |
0009-2614 |
|
dc.identifier.uri |
https://libjncir.jncasr.ac.in/xmlui/10572/2350 |
|
dc.description |
Restricted Access |
en_US |
dc.description.abstract |
A study of the visible light induced oxidation of water by perovskite oxides of the formula LaMO3 (M = transition metal) has revealed the best activity with LaCoO3 which contains Co3+ in the intermediate-spin (IS) with one e(g) electron. Among the rare earth manganites, only orthorhombic manganites with octahedral Mn3+ ions exhibit good catalytic activity, but hexagonal manganites are poor catalysts. Interestingly, not only the perovskite rare earth cobaltites but also solid solutions of Co3+ in cubic rare earth sesquioxides exhibit catalytic activity comparable to LaCoO3, the Co3+ ion in all these oxides also being in the IS t(2g)(5)e(g)(1) state. (C) 2013 Elsevier B. V. All rights reserved. |
en_US |
dc.description.uri |
1873-4448 |
en_US |
dc.description.uri |
http://dx.doi.org/10.1016/j.cplett.2013.10.089 |
en_US |
dc.language.iso |
English |
en_US |
dc.publisher |
Elsevier Science Bv |
en_US |
dc.rights |
@Elsevier Science Bv, 2014 |
en_US |
dc.subject |
Physical Chemistry |
en_US |
dc.subject |
Atomic, Molecular & Chemical Physics |
en_US |
dc.subject |
Oxygen-Evolving Catalysts |
en_US |
dc.subject |
Structural Requirements |
en_US |
dc.subject |
Manganese Oxides |
en_US |
dc.subject |
Efficient |
en_US |
dc.subject |
Evolution |
en_US |
dc.subject |
Challenges |
en_US |
dc.subject |
Principles |
en_US |
dc.title |
Visible light induced oxidation of water by rare earth manganites, cobaltites and related oxides |
en_US |
dc.type |
Article |
en_US |