A hexanuclear Cu(I) cluster supported by cuprophilic interaction: effects of aromatics on luminescence properties

Chakraborty, Anindita; Ramachandran, Krishna Kumar; Yamijala, Sharma S. R. K. C.; Pati, Swapan Kumar; Maji, Tapas Kumar

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dc.contributor.author	Chakraborty, Anindita
dc.contributor.author	Ramachandran, Krishna Kumar
dc.contributor.author	Yamijala, Sharma S. R. K. C.
dc.contributor.author	Pati, Swapan Kumar
dc.contributor.author	Maji, Tapas Kumar
dc.date.accessioned	2017-02-21T07:02:08Z
dc.date.available	2017-02-21T07:02:08Z
dc.date.issued	2014
dc.identifier.citation	Chakraborty, A; Ramachandran, KK; Yamijala, SSRKC; Pati, SK; Maji, TK, A hexanuclear Cu(I) cluster supported by cuprophilic interaction: effects of aromatics on luminescence properties. RSC Advances 2014, 4 (66) 35167-35170, http://dx.doi.org/10.1039/c4ra06183g	en_US
dc.identifier.citation	RSC Advances	en_US
dc.identifier.citation	4	en_US
dc.identifier.citation	66	en_US
dc.identifier.issn	2046-2069
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/2427
dc.description	Restricted Access	en_US
dc.description.abstract	A hexanuclear Cu(I) cluster {Cu-3(L)(2)}(2) (1) based on a novel tripodal linker (L) has been synthesized. 1 shows intense emission (lambda(max) 560 nm) with lifetime <tau > = 224 ms and quantum yield = 27.6%. The emission is highly sensitive towards different electron rich and electron deficient aromatics. DFT calculations were performed to understand the origin of emission and sensing properties.	en_US
dc.description.uri	http://dx.doi.org/10.1039/c4ra06183g	en_US
dc.language.iso	English	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.rights	@Royal Society of Chemistry, 2014	en_US
dc.subject	Chemistry	en_US
dc.subject	Ray Crystal-Structures	en_US
dc.subject	Copper(I) Selenolate	en_US
dc.subject	Phosphine-Ligands	en_US
dc.subject	Complexes	en_US
dc.subject	Coordination	en_US
dc.subject	Carboxylate	en_US
dc.subject	Reactivity	en_US
dc.subject	Discrete	en_US
dc.subject	Polymers	en_US
dc.subject	Sensors	en_US
dc.title	A hexanuclear Cu(I) cluster supported by cuprophilic interaction: effects of aromatics on luminescence properties	en_US
dc.type	Article	en_US