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Mg-MOF-74@SBA-15 hybrids: Synthesis, characterization, and adsorption properties

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dc.contributor.author Chakraborty, Anindita
dc.contributor.author Maji, Tapas Kumar
dc.date.accessioned 2017-02-21T07:02:08Z
dc.date.available 2017-02-21T07:02:08Z
dc.date.issued 2014
dc.identifier.citation Chakraborty, A; Maji, TK, Mg-MOF-74@SBA-15 hybrids: Synthesis, characterization, and adsorption properties. APL Materials 2014, 2 (12), 124107 http://dx.doi.org/10.1063/1.4902816 en_US
dc.identifier.citation APL Materials en_US
dc.identifier.citation 2 en_US
dc.identifier.citation 12 en_US
dc.identifier.issn 2166-532X
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/2432
dc.description Open Access en_US
dc.description.abstract Nanocrystals of Mg-MOF-74 have been immobilized into the mesopores of SBA-15 rods to fabricate Mg-MOF-74@SBA-15 hybrid materials. To furnish such composites, a relatively simple synthetic strategy has been adopted by direct dispersion of the metal-organic framework (MOF) precursors in SBA-15 matrix to prepare the hybrid materials in situ. The hybrid materials have been characterized using powder X-ray diffraction and several spectroscopic and microscopic techniques, which suggest growth of the MOF nanocrystals inside the SBA-15 mesopores and the composites exhibit characteristics of both the components. N-2 adsorption isotherms at 77 K reveal that the composites contain additional mesopores, compared to only micropores of pristine MOF nanocrystals. In addition to such combination of both micro and mesoporosity, the composites also demonstrate significant CO2 adsorption at room temperature. (C) 2014 Author(s). en_US
dc.description.uri http://dx.doi.org/10.1063/1.4902816 en_US
dc.language.iso English en_US
dc.publisher American Institute of Physics en_US
dc.rights @American Institute of Physics, 2014 en_US
dc.subject Nanoscience & Nanotechnology en_US
dc.subject Materials Science en_US
dc.subject Applied Physics en_US
dc.subject Metal-Organic Frameworks en_US
dc.subject Mesoporous Silica en_US
dc.subject Nanocrystals en_US
dc.subject Mof en_US
dc.title Mg-MOF-74@SBA-15 hybrids: Synthesis, characterization, and adsorption properties en_US
dc.type Article en_US


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