dc.contributor.author |
Haldar, Ritesh
|
|
dc.contributor.author |
Matsuda, Ryotaro
|
|
dc.contributor.author |
Kitagawa, Susumu
|
|
dc.contributor.author |
George, Subi Jacob
|
|
dc.contributor.author |
Maji, Tapas Kumar
|
|
dc.date.accessioned |
2017-02-21T09:00:04Z |
|
dc.date.available |
2017-02-21T09:00:04Z |
|
dc.date.issued |
2014 |
|
dc.identifier.citation |
Haldar, R; Matsuda, R; Kitagawa, S; George, SJ; Maji, TK, Amine-Responsive Adaptable Nanospaces: Fluorescent Porous Coordination Polymer for Molecular Recognition. Angewandte Chemie-International Edition 2014, 53 (44) 11772-11777, http://dx.doi.org/10.1002/anie.201405619 |
en_US |
dc.identifier.citation |
Angewandte Chemie-International Edition |
en_US |
dc.identifier.citation |
53 |
en_US |
dc.identifier.citation |
44 |
en_US |
dc.identifier.issn |
1433-7851 |
|
dc.identifier.uri |
https://libjncir.jncasr.ac.in/xmlui/10572/2515 |
|
dc.description |
Restricted Access |
en_US |
dc.description.abstract |
Flexible and dynamic porous coordination polymers (PCPs) with well-defined nanospaces composed of chromophoric organic linkers provide a scaffold for encapsulation of versatile guest molecules through noncovalent interactions. PCPs thus provide a potential platform for molecular recognition. Herein, we report a flexible 3D supramolecular framework {[Zn(ndc)(o-phen)]center dot DMF}(n) (o-phen= 1,10-phenanthroline, ndc=2,6-napthalenedicarboxylate) with confined nanospaces that can accommodate different electron-donating aromatic amine guests with selective turn-on emission signaling. This system serves as a molecular recognition platform through an emission-readout process. Such unprecedented tunable emission with different amines is attributed to its emissive charge-transfer (CT) complexation with o-phen linkers. In certain cases this CT emission is further amplified by energy transfer from the chromophoric linker unit ndc, as evidenced by single-crystal X-ray structural characterization. |
en_US |
dc.description.uri |
1521-3773 |
en_US |
dc.description.uri |
http://dx.doi.org/10.1002/anie.201405619 |
en_US |
dc.language.iso |
English |
en_US |
dc.publisher |
Wiley-V C H Verlag Gmbh |
en_US |
dc.rights |
@Wiley-V C H Verlag Gmbh, 2014 |
en_US |
dc.subject |
Chemistry |
en_US |
dc.subject |
Charge Transfer |
en_US |
dc.subject |
Energy Transfer |
en_US |
dc.subject |
Molecular Recognition |
en_US |
dc.subject |
Supramolecular Encapsulation |
en_US |
dc.subject |
X-Ray Diffraction |
en_US |
dc.subject |
Metal-Organic Frameworks |
en_US |
dc.subject |
Selective Co2 Capture |
en_US |
dc.subject |
Charge-Transfer |
en_US |
dc.subject |
Energy-Transfer |
en_US |
dc.subject |
Microporous Metal |
en_US |
dc.subject |
Adsorption |
en_US |
dc.subject |
Separation |
en_US |
dc.subject |
Transformation |
en_US |
dc.subject |
Luminescence |
en_US |
dc.subject |
Temperature |
en_US |
dc.title |
Amine-Responsive Adaptable Nanospaces: Fluorescent Porous Coordination Polymer for Molecular Recognition |
en_US |
dc.type |
Article |
en_US |