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Novel supramolecular design strategies for electronic and chiroptical functions

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dc.contributor.advisor George, Subi J.
dc.contributor.author Narayan, Bhawani
dc.date.accessioned 2019-07-18T11:20:50Z
dc.date.available 2019-07-18T11:20:50Z
dc.date.issued 2015-06-17
dc.identifier.citation Narayan, Bhawani. 2015, Novel supramolecular design strategies for electronic and chiroptical functions, Ph.D thesis, Jawaharlal Nehru Centre for Advanced Scientific Research, Bengaluru en_US
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/handle/10572/2669
dc.description.abstract This aims at highlighting the various design strategies for self-assembled π- conjugated systems dealt with in the thesis entitled ‘Novel Supramolecular Design Strategies for Electronic and Chiroptical Functions.’ Three main design strategies have been used throughout the thesis, namely, the amphiphilic design strategy, C3-symmetric 1,3,5 benzenetricarboxamide based multichromophoric design strategy and the trans-1,2- cyclohexanediamide based bischromophoric design strategy. The amphiphilic design renders stability to the self-assembled chromophores by synergistic π-π and hydrophobic interactions, and improves the ordering of the self-assembled π-conjugated systems. This ordering tremendously improves the electronic properties of the assemblies. The C3- symmetric design strategy based on 1,3,5 Benzenetricarboxamide (BTA) core reinforces the assemblies by multiple H-bonding and provides directional self-assembly. The trans- 1,2-cyclohexanediamide based bischromophoric design strategy, on the other hand, is mainly employed for chiroptical functionality. These moieties have a strong chiral preference and thereby possess the ability of homochiral recognition. This design has been employed to create assemblies for both chiroptical and electronic functionality through chirality driven formation of mixed and orthogonal donor-acceptor stacks. en_US
dc.language.iso English en_US
dc.publisher Jawaharlal Nehru Centre for Advanced Scientific Research en_US
dc.rights © 2015 JNCASR
dc.subject Supramolecular design en_US
dc.title Novel supramolecular design strategies for electronic and chiroptical functions en_US
dc.type Thesis en_US
dc.type.qualificationlevel Doctoral en_US
dc.type.qualificationname Ph.D. en_US
dc.publisher.department New Chemistry Unit (NCU) en_US


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  • Student Theses (NCU) [133]
    MS and PhD theses from New Chemistry Unit are submitted to this collection.

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