Supramolecular Organization in Lead Bromide Salts of Imidazolium-Based Ionic Liquids

Thirumurugan, A; Rao, C N R

dc.contributor.author	Thirumurugan, A
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-02-07T06:22:08Z
dc.date.available	2012-02-07T06:22:08Z
dc.date.issued	2008-05
dc.identifier	1528-7483	en_US
dc.identifier.citation	Crystal Growth & Design 8(5), 1640-1644 (2008)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/311
dc.description	Restricted Access	en_US
dc.description.abstract	By heating imidazolium bromide-based ionic liquids with lead(II) salts under ionothermal conditions, we have been able to obtain two imidazolium bromoplumbates, (EMIm)PbBr3, I, and (BMIm)(2)PbBr4, II, where EMIm and BMIm stand for 1-ethyl-3-methyl and 1-butyl-3-methyl imidazolium cations respectively. Interestingly, both these compounds exhibit unusual supramolecular organization wherein dialkylimidazolium cations arrange themselves in a cylindrical fashion giving rise to channel structures. The bromoplumbate anions reside in the channels. The lead(II) cation exhibits either hemi- or holodirected coordination geometry.	en_US
dc.description.uri	http://dx.doi.org/10.1021/cg.7010875	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.rights	© 2008 American Chemical Society	en_US
dc.subject	Ionothermal Synthesis	en_US
dc.subject	Crystal Polymorphism	en_US
dc.subject	Molten-Salt	en_US
dc.subject	Temperature	en_US
dc.subject	Crystallization	en_US
dc.subject	Cation	en_US
dc.subject	Nanoparticles	en_US
dc.subject	Nanocrystals	en_US
dc.subject	Simulations	en_US
dc.subject	Extraction	en_US
dc.title	Supramolecular Organization in Lead Bromide Salts of Imidazolium-Based Ionic Liquids	en_US
dc.type	Article	en_US