Maleate–fumarate conversion and other novel aspects of the reaction of a Co(II) maleate with pyridine and bipyridine

Padmanabhan, M; Josephx, James C; Thirumurugan, A; Rao, C N R

dc.contributor.author	Padmanabhan, M
dc.contributor.author	Josephx, James C
dc.contributor.author	Thirumurugan, A
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-02-07T06:50:37Z
dc.date.available	2012-02-07T06:50:37Z
dc.date.issued	2008
dc.identifier	1477-9226	en_US
dc.identifier.citation	Dalton Transactions (21), 2809-2811 (2008)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/316
dc.description.abstract	Reaction of a molecular Co(II) maleate, [Co(Hmal)(2)(H2O)(4)], with pyridine yields a Co(II) fumarate, [Co(fum)(H2O)(4)], with a chain structure and a chiral pyridylsuccinic acid zwitter ion, -OOC-CH(N+C5H5)-CH2-COOH, in almost quantitative yields, while the reaction of 4,4'-bipyridine (bipy) with the Co(II) maleate, on the other hand, almost quantitatively generates a polylmeric Co(II) maleate, [Co(mal)(bipy)](n) center dot(n/2) H2O along with the adduct of fumaric acid with bipyridine.	en_US
dc.description.uri	http://dx.doi.org/10.1039/b718623a	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.rights	© 2008 The Royal Society of Chemistry	en_US
dc.subject	Crystal-Structure	en_US
dc.subject	Coordination Polymers	en_US
dc.subject	Magnetic-Properties	en_US
dc.subject	Hydrothermal Synthesis	en_US
dc.subject	Metal Carboxylates	en_US
dc.subject	Open Framework	en_US
dc.subject	Maleic-Acid	en_US
dc.subject	3-D Network	en_US
dc.subject	Complexes	en_US
dc.subject	Cu(Ii)	en_US
dc.title	Maleate–fumarate conversion and other novel aspects of the reaction of a Co(II) maleate with pyridine and bipyridine	en_US
dc.type	Article	en_US