Organically-Templated Zinc and Thorium Sulfates with Chain and Layered Structures

Behera, J N; Rao, C N R

dc.contributor.author	Behera, J N
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-02-07T09:49:12Z
dc.date.available	2012-02-07T09:49:12Z
dc.date.issued	2005
dc.identifier	0044-2313	en_US
dc.identifier.citation	Zeitschrift Fur Anorganische Und Allgemeine Chemie 631(15), 3030-3036 (2005)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/327
dc.description	Restricted Access	en_US
dc.description.abstract	Amine-templated zinc sulfates of the formulae, [Zn(SO4)(H2O)(2)(C10N2H8)] (1) and [C3N2H12][Zn(SO4)] (11) both with linear structures have been prepared under hydro/solvothermal conditions. Of these, I has the chain structure formed by ZnO(4)N(2)octahedra and SO4 tetrahedra, while It comprises ladders formed by corner-sharing four-membered rings. Amine-templated thorium sulfates of the formula [HN(CH2)(6)NH](2)[Th-2(SO4)(6)(H2O)2]-2H(2)O, (III) and [H2N(CH2)(4)NH2][Th-3(SO4)(7)(H2O)4(.)5H(2)O (IV) are also obtained under hydrothermal conditions. III has a sheet structure consisting of cages whereas IV has a two-dimensional structure derived from the connectivity of ladders.	en_US
dc.description.uri	http://dx.doi.org/10.1002/zaac.200500302	en_US
dc.language.iso	en	en_US
dc.publisher	Wiley-VCH Verlag GmbH	en_US
dc.rights	© 2005 Wiley-VCH Verlag GmbH &Co	en_US
dc.subject	open-framework structures	en_US
dc.subject	zinc sulfate	en_US
dc.subject	thorium sulfate	en_US
dc.subject	hydro/solvothermal synthesis	en_US
dc.subject	Open-Framework	en_US
dc.subject	Crystal-Structure	en_US
dc.subject	Metal Selenate	en_US
dc.subject	Iron Sulfates	en_US
dc.subject	Aluminophosphate	en_US
dc.subject	Architecture	en_US
dc.subject	Networks	en_US
dc.subject	Channels	en_US
dc.subject	Kagome	en_US
dc.title	Organically-Templated Zinc and Thorium Sulfates with Chain and Layered Structures	en_US
dc.type	Article	en_US