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1,2-, 1,3- and 1,4-Benzenedicarboxylates of Cd and Zn of different dimensionalities: Process of formation of the three-dimensional structure

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dc.contributor.author Thirumurugan, A
dc.contributor.author Rao, C N R
dc.date.accessioned 2012-02-13T10:59:13Z
dc.date.available 2012-02-13T10:59:13Z
dc.date.issued 2005
dc.identifier 0959-9428 en_US
dc.identifier.citation Journal of Materials Chemistry 15(35-36), 3852-3858 (2005) en_US
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/398
dc.description.abstract A systematic study of the benzenedicarboxylates (BDCs) formed by cadmium and zinc with the three isomeric dicarboxylic acids in the presence or absence of amines has been carried out. Several BDCs have been prepared under hydrothermal conditions and their structures established by X-ray crystallography. It is pointed out that the formation of the three-dimensional structures is most favored in the case of 1,4-benzenedicarboxylic acid. An example of a Zn 1,4-BDC where the three-dimensional structure is formed favorably with the increase in reaction temperature is discussed. A one-dimensional chain structure is shown to transform to a three-dimensional structure as a function of time at an appropriate temperature. en_US
dc.description.uri http://dx.doi.org/10.1039/b504666a en_US
dc.language.iso en en_US
dc.publisher Royal Society Chemistry en_US
dc.rights © 2005 The Royal Society of Chemistry en_US
dc.subject Open-Framework Structures en_US
dc.subject Metal-Organic Frameworks en_US
dc.subject Secondary Building Units en_US
dc.subject Coordination Polymers en_US
dc.subject Zinc Phosphates en_US
dc.subject Network en_US
dc.subject Transformations en_US
dc.subject Molecules en_US
dc.subject Solids en_US
dc.subject Terephthalate en_US
dc.title 1,2-, 1,3- and 1,4-Benzenedicarboxylates of Cd and Zn of different dimensionalities: Process of formation of the three-dimensional structure en_US
dc.type Article en_US


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