Organically templated three-dimensional open-framework metal selenites with a diamondoid network

Udayakumar, D; Rao, C N R

dc.contributor.author	Udayakumar, D
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-02-16T06:20:22Z
dc.date.available	2012-02-16T06:20:22Z
dc.date.issued	2003
dc.identifier	0959-9428	en_US
dc.identifier.citation	Journal of Materials Chemistry 13(7), 1635-1638 (2003)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/444
dc.description.abstract	Three-dimensional open-framework metal selenites of the formula, [H2N(CH2)(4)NH2](0.5)[M(HSeO3)(Se2O5)] (M = Zn, Co or Ni), containing both selenite and diselenite units and intersecting 10-membered channels, have been prepared hydrothermally in the presence of piperazine. The compounds are isomorphous and crystallize in the P-1 space group. The structure is built up of MO6 dimers along with Se2O5 and HSeO3 units, the first two forming sheets, which are connected by the selenite units to yield a three-dimensional non-interpenetrating diamondoid network. The 10-membered channels have an unusual structure, being formed by 4-membered (M2Se2) and 6-membered (M2Se4) rings.	en_US
dc.description.uri	http://dx.doi.org/10.1039/b303323f	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.rights	© 2003 The Royal Society of Chemistry	en_US
dc.subject	Crystal-Structure	en_US
dc.subject	Magnetic-Properties	en_US
dc.subject	Molecular Rods	en_US
dc.subject	Diselenite	en_US
dc.subject	Crystallization	en_US
dc.subject	Sulfates	en_US
dc.subject	Channels	en_US
dc.subject	Kagome	en_US
dc.subject	Layers	en_US
dc.subject	Nets	en_US
dc.title	Organically templated three-dimensional open-framework metal selenites with a diamondoid network	en_US
dc.type	Article	en_US