Organically Templated Linear and Layered Iron Sulfates

Paul, Geo; Choudhury, Amitava; Rao, C N R

dc.contributor.author	Paul, Geo
dc.contributor.author	Choudhury, Amitava
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-02-16T10:39:08Z
dc.date.available	2012-02-16T10:39:08Z
dc.date.issued	2003-03-11
dc.identifier	0897-4756	en_US
dc.identifier.citation	Chemistry Of Materials 15(5), 1174-1180 (2003)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/449
dc.description	Restricted Access	en_US
dc.description.abstract	Linear and layered organically templated iron sulfates have been prepared under hydrothermal conditions. The linear iron sulfates, with the compositions [H3N(CH2)(2)NH3][FeF3(SO4)], I, [C(NH2)(3)](2)[FeF(SO4)(2)], II, [H3N(CH2)(2)NH2(CH2)(2)NH3][FeF(SO4)(2)], III, and [H2N(CH2)(4)NH2][FeF3SO4], IV, possess the chain topologies found in tancoite, butlerite, and sideronatrite minerals. The layered sulfate V, with the composition [H3N(CH2)(2)NH3][Fe2F2(SO4)(2)(H2O)(2)], can be considered to be formed from butlerite-type chains and with a structure similar to that of the layered fluorophosphate, ULM-10. Whereas the linear chains show the presence of antiferromagnetic interactions, the layered iron sulfate exhibits metamagnetism.	en_US
dc.description.uri	http://dx.doi.org/10.1021/cm020772p	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.rights	© 2003 American Chemical Society	en_US
dc.subject	Oxyfluorinated Microporous Compounds	en_US
dc.subject	One-Dimensional Aluminophosphate	en_US
dc.subject	Open-Framework Structures	en_US
dc.subject	Crystal-Structure	en_US
dc.subject	Temperature Crystallization	en_US
dc.subject	3-Dimensional Structures	en_US
dc.subject	Gallium Fluorophosphate	en_US
dc.subject	Hydrothermal Synthesis	en_US
dc.subject	Magnetic-Properties	en_US
dc.subject	Phosphates	en_US
dc.title	Organically Templated Linear and Layered Iron Sulfates	en_US
dc.type	Article	en_US