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Open-framework zinc and cobalt phosphates synthesized by the tributylphosphate route
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| dc.contributor.author | Neeraj, S
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| dc.contributor.author | Rao, C N R
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| dc.contributor.author | Cheetham, Anthony K
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| dc.date.accessioned | 2012-02-28T11:38:21Z | |
| dc.date.available | 2012-02-28T11:38:21Z | |
| dc.date.issued | 2004-03-07 | |
| dc.identifier | 0959-9428 | en_US |
| dc.identifier.citation | Journal of Materials Chemistry 14(5), 814-820 (2004) | en_US |
| dc.identifier.uri | https://libjncir.jncasr.ac.in/xmlui/10572/511 | |
| dc.description.abstract | By employing tributylphosphate as the source of phosphorus, several open-framework zinc and cobalt phosphates have been prepared hydrothermally. Of the three new zinc phosphates [C6N2H18][Zn(HPO4)(2)], I, has a linear chain structure while [C4N2H14][Zn-5(PO4)(4)(H2O)], II, [NH4][H3O][Zn-4(PO4)(3]2).H2O, III, have three-dimensional structures. Of the three new cobalt phosphates described, [C5N2H14][Co(HPO4)(2)], IV, and [C5N2H14][Co(HPO4)(2)], V, have linear chain structures, while [C4N2H12](3) [CO2(OH)(HPO4)(3)](2), VI, has a complex double chain structure. The study shows that the use of the organophosphate yields a variety of architectures of metal phosphates. | en_US |
| dc.description.uri | http://dx.doi.org/10.1039/b311529a | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.rights | © 2004 The Royal Society of Chemistry | en_US |
| dc.subject | Chiral Metal-Complex | en_US |
| dc.subject | Nickel(Ii) Phosphate | en_US |
| dc.subject | Aluminophosphate | en_US |
| dc.subject | Sodalite | en_US |
| dc.subject | Catalyst | en_US |
| dc.subject | Layers | en_US |
| dc.title | Open-framework zinc and cobalt phosphates synthesized by the tributylphosphate route | en_US |
| dc.type | Article | en_US |
