Synthesis, Structure, and Magnetic Properties of Amine-Templated Open-Framework Nickel(II) Sulfates

Behera, J N; Gopalkrishnan, K V; Rao, C N R

dc.contributor.author	Behera, J N
dc.contributor.author	Gopalkrishnan, K V
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-02-29T11:26:20Z
dc.date.available	2012-02-29T11:26:20Z
dc.date.issued	2004-04-19
dc.identifier	0020-1669	en_US
dc.identifier.citation	Inorganic Chemistry 43(8), 2636-2642 (2004)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/513
dc.description	Restricted Access	en_US
dc.description.abstract	Two organically templated nickel sulfates of the compositions [C4N2H12][Ni3F2(SO4)(3)(H2O)(2)] (I) and [C4N2H12][Ni2F4-(SO4)H2O] (II) with open architectures have been synthesized under hydro/solvothermal conditions in the presence of piperazine. I has a layered structure formed by sinusoidal chains comprising hexameric units, whereas II has a three-dimensional structure with 10-membered channels. The layered Ni(II) sulfate, I, is ferrimagnetic, exhibiting hysteresis at low temperatures. The three-dimensional Ni(II) sulfate, II, is essentially paramagnetic. We have also obtained layered compounds isostructural with I containing other amines.	en_US
dc.description.uri	http://dx.doi.org/10.1021/ic035488u	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.rights	© 2004 American Chemical Society	en_US
dc.subject	Crystal-Structure	en_US
dc.subject	Metal Selenites	en_US
dc.subject	Iron Sulfates	en_US
dc.subject	Ring Channels	en_US
dc.subject	Phosphate	en_US
dc.subject	Networks	en_US
dc.subject	Kagome	en_US
dc.subject	3d	en_US
dc.title	Synthesis, Structure, and Magnetic Properties of Amine-Templated Open-Framework Nickel(II) Sulfates	en_US
dc.type	Article	en_US