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Synthesis, Structure, and the Unusual Magnetic Properties of an Amine-Templated Iron(II) Sulfate Possessing the Kagome Lattice

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dc.contributor.author Rao, C N R
dc.contributor.author Sampathkumaran, E V
dc.contributor.author Nagarajan, R
dc.contributor.author Paul, Geo
dc.contributor.author Behera, J N
dc.contributor.author Choudhury, Amitava
dc.date.accessioned 2012-03-01T06:37:49Z
dc.date.available 2012-03-01T06:37:49Z
dc.date.issued 2004-04-20
dc.identifier 0897-4756 en_US
dc.identifier.citation Chemistry Of Materials 16(8), 1441-1446 (2004) en_US
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/517
dc.description Restricted Access en_US
dc.description.abstract An amine-templated iron(II) sulfate of the composition [H3N(CH2)(6)NH3] [(Fe1.5F3)-F-II(SO4)].0.5H(2)O, 1, representing an example of a Kagome lattice with Fe in the +2 state, has been synthesized under solvothermal conditions. Having determined the structure by single-crystal X-ray diffraction, the oxidation state of iron was established by Mossbauer spectroscopy. The magnetic properties of the Fe(II) Kagome compound are rather unusual in that it undergoes ferrimagnetic ordering below 19 K and does not exhibit spin-glass freezing. en_US
dc.description.uri http://dx.doi.org/10.1021/cm035304+ en_US
dc.language.iso en en_US
dc.publisher American Chemical Society en_US
dc.rights © 2004 American Chemical Society en_US
dc.subject Bond-Valence Parameters en_US
dc.subject Antiferromagnet en_US
dc.subject Spin en_US
dc.subject Jarosites en_US
dc.subject Networks en_US
dc.title Synthesis, Structure, and the Unusual Magnetic Properties of an Amine-Templated Iron(II) Sulfate Possessing the Kagome Lattice en_US
dc.type Article en_US


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