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A layered chlorophosphate, Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)], containing Na+ ions in the interlamellar space
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| dc.contributor.author | Jayaraman, Krishnamoorthy
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| dc.contributor.author | Choudhury, Amitava
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| dc.contributor.author | Vaidhyanathan, Ramanathan
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| dc.contributor.author | Rao, C N R
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| dc.date.accessioned | 2012-03-02T10:44:54Z | |
| dc.date.available | 2012-03-02T10:44:54Z | |
| dc.date.issued | 2001-09 | |
| dc.identifier | 1144-0546 | en_US |
| dc.identifier.citation | New Journal Of Chemistry 25(9), 1199-1202 (2001) | en_US |
| dc.identifier.uri | https://libjncir.jncasr.ac.in/xmlui/10572/532 | |
| dc.description.abstract | Reaction between CdCl2.H2O and NaH2PO4.H2O Under hydrothermal conditions gives rise to a new cadmium chlorophosphate of the formula Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)] I. This material crystallizes in the orthorhombic system with space group Fmm2(no. 42). I has macroanionic layers of [Cd4Cl3(HPO4)(2)(H2PO4)(4)](3-) with Na+ ions in the interlamellar space. The discovery of such compounds suggests that metathetic reactions carried out under hydrothermal conditions may provide a novel route for the synthesis of new open-framework structures. | en_US |
| dc.description.uri | http://dx.doi.org/10.1039/B103278J | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.rights | © 2001 The Royal Society of Chemistry | en_US |
| dc.subject | Frameworks Mil-N | en_US |
| dc.subject | Crystal-Structure | en_US |
| dc.subject | Phosphates | en_US |
| dc.subject | Series | en_US |
| dc.title | A layered chlorophosphate, Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)], containing Na+ ions in the interlamellar space | en_US |
| dc.type | Article | en_US |
