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A zinc phosphate oxalate with phosphate layers pillared by the oxalate units
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| dc.contributor.author | Neeraj, S
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| dc.contributor.author | Natarajan, Srinivasan
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| dc.contributor.author | Rao, C N R
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| dc.date.accessioned | 2012-03-02T11:11:02Z | |
| dc.date.available | 2012-03-02T11:11:02Z | |
| dc.date.issued | 2001 | |
| dc.identifier | 1472-7773 | en_US |
| dc.identifier.citation | Journal Of The Chemical Society-Dalton Transactions (3), 289-291 (2001) | en_US |
| dc.identifier.uri | https://libjncir.jncasr.ac.in/xmlui/10572/535 | |
| dc.description.abstract | An open-framework phosphate oxalate of zinc, of composition [NH3(CH2)(3)NH3][Zn-6(PO4)(4)(C2O4)], 1, has been synthesized, for the first time, employing hydrothermal methods in the presence of ethylenediamine. The structure comprises a network of Zn(1)O-5, Zn(2)O-4, Zn(3)O-5 polyhedra and PO4 tetrahedra connected through their vertices forming neutral layers bridged by the oxalate units, giving one-dimensional channels. The presence of Zn in tetrahedral, trigonal-bipyramidal and square-pyramidal coordinations, and the formation of neutral layers, are noteworthy features. | en_US |
| dc.description.uri | http://dx.doi.org/10.1039/B007980O | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.rights | © 2001 The Royal Society of Chemistry | en_US |
| dc.subject | coordination chemistry | en_US |
| dc.subject | hydrothermal synthesis | en_US |
| dc.subject | structural studies | en_US |
| dc.subject | X-ray diffraction | en_US |
| dc.subject | X-ray powder diffraction | en_US |
| dc.subject | zinc | en_US |
| dc.subject | Phosphatooxalate | en_US |
| dc.subject | Chains | en_US |
| dc.title | A zinc phosphate oxalate with phosphate layers pillared by the oxalate units | en_US |
| dc.type | Article | en_US |
