A zinc phosphate oxalate with phosphate layers pillared by the oxalate units

Neeraj, S; Natarajan, Srinivasan; Rao, C N R

dc.contributor.author	Neeraj, S
dc.contributor.author	Natarajan, Srinivasan
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-03-02T11:11:02Z
dc.date.available	2012-03-02T11:11:02Z
dc.date.issued	2001
dc.identifier	1472-7773	en_US
dc.identifier.citation	Journal Of The Chemical Society-Dalton Transactions (3), 289-291 (2001)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/535
dc.description.abstract	An open-framework phosphate oxalate of zinc, of composition [NH3(CH2)(3)NH3][Zn-6(PO4)(4)(C2O4)], 1, has been synthesized, for the first time, employing hydrothermal methods in the presence of ethylenediamine. The structure comprises a network of Zn(1)O-5, Zn(2)O-4, Zn(3)O-5 polyhedra and PO4 tetrahedra connected through their vertices forming neutral layers bridged by the oxalate units, giving one-dimensional channels. The presence of Zn in tetrahedral, trigonal-bipyramidal and square-pyramidal coordinations, and the formation of neutral layers, are noteworthy features.	en_US
dc.description.uri	http://dx.doi.org/10.1039/B007980O	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.rights	© 2001 The Royal Society of Chemistry	en_US
dc.subject	coordination chemistry	en_US
dc.subject	hydrothermal synthesis	en_US
dc.subject	structural studies	en_US
dc.subject	X-ray diffraction	en_US
dc.subject	X-ray powder diffraction	en_US
dc.subject	zinc	en_US
dc.subject	Phosphatooxalate	en_US
dc.subject	Chains	en_US
dc.title	A zinc phosphate oxalate with phosphate layers pillared by the oxalate units	en_US
dc.type	Article	en_US