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Open-Framework Cadmium Succinates with Interpenetrating Frameworks Formed by Tetrahedral [ClCd4O24] and [BrCd4O24] Clusters
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| dc.contributor.author | Vaidhyanathan, R
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| dc.contributor.author | Natarajan, Srinivasan
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| dc.contributor.author | Rao, C N R
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| dc.date.accessioned | 2012-03-14T05:52:51Z | |
| dc.date.available | 2012-03-14T05:52:51Z | |
| dc.date.issued | 2003-01 | |
| dc.identifier | 1528-7483 | en_US |
| dc.identifier.citation | Crystal Growth & Design 3(1), 47-51 (2003) | en_US |
| dc.identifier.uri | https://libjncir.jncasr.ac.in/xmlui/10572/601 | |
| dc.description | Restricted Access | en_US |
| dc.description.abstract | By carrying out a metathetic reaction between sodium succinate and CdCl2 or CdBr2 in an n-butanol-water mixture, two novel open-framework cadmium succinates, [Na3Cd5(C4H4O4)(6)Cl], I and {Na3Cd5(C4H4O4)(6)Br], II, have been isolated. Both of these compounds possess interpenetrating three-dimensional open-framework structures wherein tetrahedral Cl(Br)Cd4O24 clusters are connected by succinate linkages. The tetrahedral cluster itself is formed of four CdO6 octahedra surrounding a halogen atom. The three-dimensional cadmium succinate framework incorporates sodium ions. Four sodiums surround the second nearest neighbor halogen atom, forming a Na4Cl(Br) tetrahedron. | en_US |
| dc.description.uri | http://dx.doi.org/10.1021/cg0200309 | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.rights | © 2003 American Chemical Society | en_US |
| dc.subject | Secondary Building Units | en_US |
| dc.subject | Crystal-Structures | en_US |
| dc.subject | Solids | en_US |
| dc.subject | Design | en_US |
| dc.title | Open-Framework Cadmium Succinates with Interpenetrating Frameworks Formed by Tetrahedral [ClCd4O24] and [BrCd4O24] Clusters | en_US |
| dc.type | Article | en_US |
