dc.contributor.author |
Ayi, Ayi A
|
|
dc.contributor.author |
Choudhury, Amitava
|
|
dc.contributor.author |
Natarajan, Srinivasan
|
|
dc.contributor.author |
Rao, C N R
|
|
dc.date.accessioned |
2012-03-19T08:56:06Z |
|
dc.date.available |
2012-03-19T08:56:06Z |
|
dc.date.issued |
2000 |
|
dc.identifier |
0959-9428 |
en_US |
dc.identifier.citation |
Journal of Materials Chemistry 10(11), 2606-2609 (2000) |
en_US |
dc.identifier.uri |
https://libjncir.jncasr.ac.in/xmlui/10572/662 |
|
dc.description.abstract |
A new open-framework zinc phosphate of the formula [C2H5NH3](2)[Zn-2(HPO4)(3)], I, has been synthesized at 60 degreesC in a THF-water medium in the presence of ethylamine. The structure consists of a network of strictly alternating ZnO4 and PO4 tetrahedra forming 4- and 8-membered rings, which connect to form intersecting elliptical channels bound by 12- and 8-T atoms (T = Zn, P) along the c and b axes, respectively. The amine molecule sits in the channel bound by 12-T atoms and the -OH group of the HPO4 unit protrudes into the 8-membered channel. An interesting feature of I is that it has a very low framework density. Crystal data: [C2H5NH3](2)[Zn-2(HPO4)(3)], monoclinic, C2/c (no. 15), a = 17.351(4), b = 9.507(5), c = 9.806(5) Angstrom, beta = 102.68(2)degrees, V = 1578.3(1) Angstrom (3), Z = 4. |
en_US |
dc.description.uri |
http://dx.doi.org/10.1039/B004972G |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Royal Society of Chemistry |
en_US |
dc.rights |
© 2000 The Royal Society of Chemistry |
en_US |
dc.subject |
Solution-mediated synthesis |
en_US |
dc.subject |
Zinc phosphate |
en_US |
dc.subject |
Open-framework material |
en_US |
dc.subject |
Directing Organic Amines |
en_US |
dc.subject |
Temperature Synthesis |
en_US |
dc.subject |
Large-Pore |
en_US |
dc.subject |
Framework |
en_US |
dc.subject |
Chains |
en_US |
dc.subject |
Layers |
en_US |
dc.subject |
Phases |
en_US |
dc.subject |
Family |
en_US |
dc.title |
Solution-mediated synthesis of a three-dimensional zinc phosphate in the presence of a monoamine |
en_US |
dc.type |
Article |
en_US |