Unusual dual role of the organic amine in an open-framework structure

Vaidhyanathan, R; Natarajan, Srinivasan; Rao, C N R

dc.contributor.author	Vaidhyanathan, R
dc.contributor.author	Natarajan, Srinivasan
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-03-20T09:09:05Z
dc.date.available	2012-03-20T09:09:05Z
dc.date.issued	1999-11
dc.identifier	0959-9428	en_US
dc.identifier.citation	Journal of Materials Chemistry 9(11), 2789-2793 (1999)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/683
dc.description.abstract	The hydrothermal synthesis and single crystal structure determination of a new open-framework zinc phosphate, [NH3(CH2)(3)NH3](2)[NH3(CH2)(3)NH2](2)[Zn-12(OH2)(2)(PO4)(10)]. H2O, is reported. Crystal data: monoclinic, space group Pn (no. 7), a=13.092(2), b=14.272(2), c=14.220(1) Angstrom, beta=90.3(2)degrees, V=2656.9(1) Angstrom(3), Z=2, M=1927.6, R=0.04. The structure is made up of tetrahedral linkages between ZnO4, ZnO3N and PO4 moieties forming distinct channels. The structure-directing amine is present in two distinct forms, in the free state and as a ligand to zinc, the two species occurring in distinct channels.	en_US
dc.description.uri	http://dx.doi.org/10.1039/A905506A	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.rights	© 1999 The Royal Society of Chemistry	en_US
dc.subject	Crystal-Structure	en_US
dc.subject	Zinc Phosphate	en_US
dc.subject	Zeolite	en_US
dc.title	Unusual dual role of the organic amine in an open-framework structure	en_US
dc.type	Article	en_US