An open-framework iron phosphate with large voids, exhibiting spin-crossover

Choudhury, Amitava; Natarajan, Srinivasan; Rao, C N R

dc.contributor.author	Choudhury, Amitava
dc.contributor.author	Natarajan, Srinivasan
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-03-21T05:51:04Z
dc.date.available	2012-03-21T05:51:04Z
dc.date.issued	1999-07-21
dc.identifier	1359-7345	en_US
dc.identifier.citation	Chemical Communications (14), 1305-1306 (1999)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/692
dc.description.abstract	A novel iron phosphate, [(C4N3H16)(C4N3H15)](5+)-[Fe5F4(H2PO4)(HPO4)(3)(PO4)(3)](5-). H2O, consisting of a Fe-O/F-Fe network crosslinked by PO4 groups is shown to possess unusually large elliptical voids of 24 T atoms (T = Fe, P) and to exhibit a gradual low- to high-spin transformation.	en_US
dc.description.uri	http://dx.doi.org/10.1039/A903683K	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.rights	© 1999 The Royal Society of Chemistry	en_US
dc.subject	Hydrothermal Synthesis	en_US
dc.subject	Magnetic-Properties	en_US
dc.subject	Crystal-Structure	en_US
dc.title	An open-framework iron phosphate with large voids, exhibiting spin-crossover	en_US
dc.type	Article	en_US