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An ultraviolet photoelectron spectroscopic study of BF3–donor complexes

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dc.contributor.author Pradeep, T
dc.contributor.author Sreekanth, C S
dc.contributor.author Rao, C N R
dc.date.accessioned 2012-03-26T11:26:49Z
dc.date.available 2012-03-26T11:26:49Z
dc.date.issued 1989-04-01
dc.identifier 0021-9606 en_US
dc.identifier.citation Journal of Chemical Physics 90(9), 4704-4708 (1989) en_US
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/741
dc.description Restricted Access en_US
dc.description.abstract He i spectra of strong n–v type adducts of BF3 with H2O, CH3OH, (C2H5)2O, and CH3CN as well as of weak complexes of BF3 with NO and H2S are reported along with assignments based on MO calculations. The energy of the fluorine orbitals of BF3 is shown to be shifted in proportion to the strength of the donor–acceptor interaction. BF3 seems to form a contact pair with CS2. en_US
dc.description.uri http://dx.doi.org/10.1063/1.456616 en_US
dc.language.iso en en_US
dc.publisher American Institute of Physics en_US
dc.rights © 1989 American Institute of Physics en_US
dc.subject Photoelectron Spectroscopy en_US
dc.subject Boron Fluorides en_US
dc.subject Donors en_US
dc.subject Acceptors en_US
dc.subject Adducts en_US
dc.subject Water en_US
dc.subject Methanol en_US
dc.subject Ethyl Ether en_US
dc.subject Methyl Compounds en_US
dc.subject Organic Nitrogen Compounds en_US
dc.subject Dissociation Energy en_US
dc.subject Molecular Clusters en_US
dc.subject Complexes en_US
dc.subject Hydrogen Sulfides en_US
dc.subject Nitric Oxide en_US
dc.title An ultraviolet photoelectron spectroscopic study of BF3–donor complexes en_US
dc.type Article en_US


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