Synthesis And Structural Characterization Of A Chiral Open-Framework Tin(Ii) Phosphate, [Cn3h6][Sn4p3o12] (Guan-Snpo)

Ayyappan, S; Bu, X; Cheetham, A K; Rao, C N R

dc.contributor.author	Ayyappan, S
dc.contributor.author	Bu, X
dc.contributor.author	Cheetham, A K
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-11-06T11:07:44Z
dc.date.available	2012-11-06T11:07:44Z
dc.date.issued	1998-11
dc.identifier	0897-4756	en_US
dc.identifier.citation	Chemistry Of Materials 10(11), 3308-3310 (1998)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/923
dc.description	Restricted Access	en_US
dc.description.abstract	A chiral open-framework tin phosphate structure, [CN3H6][Sn4P3O12], has been obtained by using an achiral structure-directing agent, guanidine. The structures of both enantiomorphs have been determined: tetragonal, space groups P4(3) (No. 78) and P4(1) (No. 76), a = 8.8881(1) Angstrom, c = 20.6029(4) Angstrom, V = 1627.59 (4) Angstrom(3), Z = 4, M = 819.76. The framework, which is composed of puckered 6-membered (Sn3P3O6) and 12-membered (Sn6P6O12) rings, accommodates the organic cation in a tortuous chiral channel.	en_US
dc.description.uri	http://dx.doi.org/10.1021/cm980559m	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.rights	© 1998 American Chemical Society	en_US
dc.subject	Experimental study	en_US
dc.subject	Chemical preparation	en_US
dc.subject	Hydrothermal synthesis	en_US
dc.subject	Molecular sieve	en_US
dc.subject	Organic cation	en_US
dc.subject	Guanidinium compounds	en_US
dc.subject	Tin complex	en_US
dc.subject	Phosphato complex	en_US
dc.subject	Anionic complex	en_US
dc.subject	Hydrogen bond	en_US
dc.subject	X ray diffraction	en_US
dc.subject	Crystalline structure	en_US
dc.subject	Polynuclear complex	en_US
dc.subject	Channel structure	en_US
dc.subject	Inorganic compound	en_US
dc.title	Synthesis And Structural Characterization Of A Chiral Open-Framework Tin(Ii) Phosphate, [Cn3h6][Sn4p3o12] (Guan-Snpo)	en_US
dc.type	Article	en_US