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A MAS NMR investigation of lead phosphosilicate glasses: The nature of the highly deshielded six-coordinated silicon

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dc.contributor.author Prabakar, S
dc.contributor.author Rao, K J
dc.contributor.author Rao, C N R
dc.date.accessioned 2012-11-06T11:36:37Z
dc.date.available 2012-11-06T11:36:37Z
dc.date.issued 1991-04
dc.identifier 0025-5408 en_US
dc.identifier.citation Materials Research Bulletin 26(4), 285-294 (1991) en_US
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/931
dc.description Restricted Access en_US
dc.description.abstract Si-29 and P-31 NMR spectra have been studied in a series of lead phosphosilicate glasses. It is found that as the P2O5 content increases, the signal due to the six-coordinated silicon at - 212 ppm grows in intensity. Based on partial charge arguments it is suggested that the six-coordinated silicon atoms are surrounded by only phosphorus as second neighbours and are highly desheilded. en_US
dc.description.uri http://dx.doi.org/10.1016/0025-5408(91)90023-F en_US
dc.language.iso en en_US
dc.publisher Pergamon-Elsevier Science Ltd en_US
dc.rights © 1991 Pergamon Press Ltd en_US
dc.subject Silicon en_US
dc.subject Lead en_US
dc.subject Phosphosilicates en_US
dc.subject Oxides en_US
dc.subject Glasses en_US
dc.title A MAS NMR investigation of lead phosphosilicate glasses: The nature of the highly deshielded six-coordinated silicon en_US
dc.type Article en_US


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