Electron states of the HCI dimer

Pradeep, T; Rao, C N R

dc.contributor.author	Pradeep, T
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-11-07T09:09:26Z
dc.date.available	2012-11-07T09:09:26Z
dc.date.issued	1991-11-15
dc.identifier	0021-9606	en_US
dc.identifier.citation	Journal of Chemical Physics 95(10), 7389-7391 (1991)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/933
dc.description	Restricted Access	en_US
dc.description.abstract	The He i photoelectron spectrum of HCl dimer has been recorded and the observed ionizations at 12.3, 13.6, 15.1 and 17.0 eV have been assigned to different orbitals on the basis of molecular orbital calculations. The observed first adiabatic IE (11.9 eV) agree well with the value of 11.91 eV from a photoionization study of the dimer. The two HCl units in the dimer are nonequivalent and there is significant interaction between the sigma-orbitals. Both the calculations and the experiment show that the geometry undergoes considerable distortion on ionization.	en_US
dc.description.uri	http://dx.doi.org/10.1063/1.461364	en_US
dc.language.iso	en	en_US
dc.publisher	American Institute of Physics	en_US
dc.rights	© 1991 American Institute of Physics	en_US
dc.subject	Hydrogen-Bonded Dimers	en_US
dc.subject	Photoelectron-Spectroscopy	en_US
dc.subject	Spectrum	en_US
dc.subject	Ionization	en_US
dc.subject	Complexes	en_US
dc.subject	Energies	en_US
dc.subject	Hf	en_US
dc.title	Electron states of the HCI dimer	en_US
dc.type	Article	en_US