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An investigation of the first-order spin-state transition in Fe(Phen)(2)(NCS)(2) EXAFS and infrared spectroscopy
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| dc.contributor.author | Sankar, G
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| dc.contributor.author | Thomas, John Meurig
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| dc.contributor.author | Varma, Vijay
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| dc.contributor.author | Kulkarni, G U
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| dc.contributor.author | Rao, C N R
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| dc.date.accessioned | 2012-11-08T06:38:23Z | |
| dc.date.available | 2012-11-08T06:38:23Z | |
| dc.date.issued | 1996-03-15 | |
| dc.identifier | 0009-2614 | en_US |
| dc.identifier.citation | Chemical Physics Letters 251(1-2), 79-83 (1996) | en_US |
| dc.identifier.uri | https://libjncir.jncasr.ac.in/xmlui/10572/946 | |
| dc.description | Restricted Access | en_US |
| dc.description.abstract | The structure of Fe(Phen)(2)(NCS)(2) has been examined across the first-order spin-state transition by EXAFS with full multiple scattering analysis. The EXAFS data at 298 K can be satisfactorily assigned to the high-spin state, but the analysis of the low-temperature data at 90 K is not entirely unequivocal, although consistent with the predominant presence of the low-spin state. That some proportion of the high-spin state remains at low temperatures, well below the first-order transition, is clearly evidenced in the infrared spectra, suggesting possible sublattice ordering. | en_US |
| dc.description.uri | http://dx.doi.org/10.1016/0009-2614(96)00071-1 | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Science BV | en_US |
| dc.rights | © 1996 Elsevier Science BV | en_US |
| dc.subject | Crossover | en_US |
| dc.subject | spin-state transition | en_US |
| dc.subject | EXAFS | en_US |
| dc.subject | infrared spectroscopy | en_US |
| dc.title | An investigation of the first-order spin-state transition in Fe(Phen)(2)(NCS)(2) EXAFS and infrared spectroscopy | en_US |
| dc.type | Article | en_US |
