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An investigation of insulating La4BaCu5O12 obtained by the reduction of metallic La4BaCu5O13.1

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dc.contributor.author Rangavittal, N
dc.contributor.author Subbanna, G N
dc.contributor.author Row, T N Guru
dc.contributor.author Rao, C N R
dc.date.accessioned 2012-11-09T06:29:31Z
dc.date.available 2012-11-09T06:29:31Z
dc.date.issued 1995-01
dc.identifier 0022-4596 en_US
dc.identifier.citation Journal of Solid State Chemistry 114(1), 95-101 (1995) en_US
dc.identifier.uri https://libjncir.jncasr.ac.in/xmlui/10572/957
dc.description Restricted Access en_US
dc.description.abstract The structure of insulating La4BaCu5O12 obtained by the reduction of metallic La4BaCu5O13.1 has been studied by using electron microscopy and high-resolution X-ray diffraction data. While La4BaCu5O13.1 (P4/m) has a tetragonal structure with the supercell ac√5 × ac√5 × ac , the reduced phase, La4BaCu5O12, is monoclinic (P2/m) with the supercell ac√5 × ac× ac√5. La4BaCu5O12 consists of CuO5 square pyramids and CuO4 square planar units, instead of CuO6 octahedra and CuO5 square pyramids as in La4BaCu5O13.1. Electron microscopic examination reveals the presence of twinning in some of the crystals of La4BaCu5O12. en_US
dc.description.uri http://dx.doi.org/10.1006/jssc.1995.1014 en_US
dc.language.iso en en_US
dc.publisher Academic Press Inc JNL Comp Subscriptions en_US
dc.rights © 1995 Academic Press Inc en_US
dc.subject Crystal-Structure en_US
dc.subject Temperature en_US
dc.subject BaLa4cu5o13+Delta en_US
dc.subject Superconductivity en_US
dc.subject Diffraction en_US
dc.subject Oxides en_US
dc.title An investigation of insulating La4BaCu5O12 obtained by the reduction of metallic La4BaCu5O13.1 en_US
dc.type Article en_US


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