Electronic Structures of Perovskite Oxides of Transition Metals of the Type LaMO3 (M = Ti-Ni) as Revealed by MSXα Investigations

Sarma, D D; Santra, A K; Rao, C N R

dc.contributor.author	Sarma, D D
dc.contributor.author	Santra, A K
dc.contributor.author	Rao, C N R
dc.date.accessioned	2012-11-16T11:46:00Z
dc.date.available	2012-11-16T11:46:00Z
dc.date.issued	1994-06
dc.identifier	0022-4596	en_US
dc.identifier.citation	Journal Of Solid State Chemistry 110(2), 393-396 (1994)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/995
dc.description	Note. Restricted Access.	en_US
dc.description.abstract	Systematic investigations of the electronic structures of MO9-6 (M = Ti-Ni) clusters, as in the LaMO3 type perovskite oxides, have been carried out by employing the multiple-scattering Xα (MSXα) method. The crystal-field splitting of the metal d level is found to increase, while the oxygen-to-metal charge-transfer energy decreases across the transition metal series. Systematic trends are also seen in the mixing (covalency) between the metal d and the oxygen 2p orbitals in the series.	en_US
dc.description.uri	http://dx.doi.org/ 10.1006/jssc.1994.1185	en_US
dc.language.iso	en	en_US
dc.publisher	Academic Press Inc JNL-Comp Subscriptions	en_US
dc.rights	© 1994 Academic Press Inc	en_US
dc.subject	Spectroscopy	en_US
dc.title	Electronic Structures of Perovskite Oxides of Transition Metals of the Type LaMO3 (M = Ti-Ni) as Revealed by MSXα Investigations	en_US
dc.type	Article	en_US