The first organically templated linear metal selenate

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Title:	The first organically templated linear metal selenate
Authors:	Pasha, Intyaj Choudhury, Amitava Rao, C N R
Keywords:	cadmium selenate organically templated material one-dimensional structure Krohnkite-type chain and thermogravimetric analysis Sulfates Phosphates Selenites
Issue Date:	Sep-2003
Publisher:	Academic Press Inc Elsevier Science
Citation:	Journal of Solid State Chemistry 174(2), 386-391 (2003)
Abstract:	An organically templated cadmium selenate of the formula [enH(2)][Cd(H2O)(2)(SeO4)(2)] I has been synthesized by carrying out the reaction between CdO and H2SeO4 in the presence of the amine in aqueous medium at 80degreesC. The structure of I involves isolated infinite [Cd(H2O)(2)(SeO4)(2)](2-) chains running along the c-axis, with the protonated ethylenediamine molecules between them. Crystal data for I are as follows: Monoclinic, space group= C2/c, a = 10.5059(7), b = 10.3605(7), c = 10.6028(7)Å, β = 94.666(2)degrees, V = 1150.25(13) Å3, z = 8, R-1 = 0.0237, wR(2) = 0.0500 (for all data). (C) 2003 Elsevier Inc. All rights reserved.
Description:	Restricted Access
URI:	https://libjncir.jncasr.ac.in/xmlui/10572/1054
Other Identifiers:	0022-4596
Appears in Collections:	Research Papers (Prof. C.N.R. Rao)

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