An organically templated open-framework cadmium selenite

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Title:	An organically templated open-framework cadmium selenite
Authors:	Pasha, Intyaj Choudhury, Amitava Rao, C N R
Keywords:	Crystal-Structure Sulfates Channels Ion
Issue Date:	Jan-2003
Publisher:	Editions Scientifiques Medicales Elsevier
Citation:	Solid State Sciences 5(1), 257-262 (2003)
Abstract:	An open-framework cadmium selenite of the composition [CdCl2(HSeO3)2](enH2) has been obtained by a solution-mediated reaction. This compound crystallizes in a monoclinic unit cell with the space group P21/c (No. 14) and the lattice parameters a=8.2888(7) Å, b=7.8071(7) Å, c=9.9430(8) Å, β=112.444(2)°, V=594.69(9), Z=4. The selenite has a layered structure containing macroanionic sheets of [CdCl2(HSeO3)2]2−, with the protonated ethylenediamine (en) molecules in the interlamellar space. This cadmium selenite is the first few members of the new family of open-framework metal selenites.
Description:	Restricted Access
URI:	https://libjncir.jncasr.ac.in/xmlui/10572/1055
Other Identifiers:	1293-2558
Appears in Collections:	Research Papers (Prof. C.N.R. Rao)

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