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Title: | An organically templated open-framework cobalt germanate |
Authors: | Julius, Njapba Ngu Choudhury, Amitava Rao, C N R |
Keywords: | 2-Dimensional Channel Network Building Units Potassium Silicate |
Issue Date: | Jan-2003 |
Publisher: | Academic Press Inc Elsevier Science |
Citation: | Journal of Solid State Chemistry 170(1), 124-129 (2003) |
Abstract: | An open-framework cobalt germanate of the formula, [Co-2(NH2(CH2)(2)NH2)(3)][Ge9O18(OH)(4)] has been prepared under solvo/hydrothermal conditions in the presence of ethylenediamine. The germanate is constructed by Ge9O18 clusters and contains eight- and ten-membered channels. Besides connecting two Co sites, the amine also acts as a bis-chelating agent and protrudes into the eight-membered channel. (C) 2002 Elsevier Science (USA). All rights reserved. |
Description: | Restricted Access |
URI: | https://libjncir.jncasr.ac.in/xmlui/10572/1056 |
Other Identifiers: | 0022-4596 |
Appears in Collections: | Research Papers (Prof. C.N.R. Rao) |
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