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Title: | A layered zinc oxalate possessing a 12-membered honeycomb aperture, stabilized by an amine and an alkali cation |
Authors: | Vaidhyanathan, R Natarajan, Srinivasan Rao, C N R |
Keywords: | crystal growth framework host-guest chemistry organic-inorganic hybrid zinc Frameworks Mil-N Directing Organic Amines Crystal-Structure Cobalt(Ii) Carboxylate Networks Magnets Design |
Issue Date: | May-2002 |
Publisher: | Editions Scientifiques Medicales Elsevier |
Citation: | Solid State Sciences 4(5), 633-639 (2002) |
Abstract: | A new layered anionic zinc oxalate of the formula, K[C6N2H13][Zn-2(C2O4)(3)].4H(2)O containing 12-membered honeycomb apertures has been synthesized hydrothermally in the presence of DABCO and K+. A noteworthy feature of the structure is the presence of 12-membered apertures, aligned in such a way as to create pseudo one-dimensional tunnels as in zeolitic structures. The amine, K+ and water molecules are present in the tunnels. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved. |
Description: | Restricted Access |
URI: | https://libjncir.jncasr.ac.in/xmlui/10572/1064 |
Other Identifiers: | 1293-2558 |
Appears in Collections: | Research Papers (Prof. C.N.R. Rao) |
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