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dc.contributor.authorGomathi, A-
dc.contributor.authorSundaresan, A-
dc.contributor.authorRao, C N R-
dc.date.accessioned2012-12-03T11:00:07Z-
dc.date.available2012-12-03T11:00:07Z-
dc.date.issued2007-01-
dc.identifier0022-4596en_US
dc.identifier.citationJournal of Solid State Chemistry 180(1), 291-295 (2007)en_US
dc.identifier.urihttps://libjncir.jncasr.ac.in/xmlui/10572/1190-
dc.descriptionRestricted Accessen_US
dc.description.abstractWe have been able to prepare nanoparticles (∼4 nm diameter) of cubic γ-Mo2N by a simple procedure involving the reaction of MoCl5 with urea at 873 K. The nanoparticles show a superconducting transition around 6.5 K. The γ-Mo2N nanoparticles are readily transformed to nanoparticles of δ-MoN with a slightly larger diameter on heating in a NH3 atmosphere at 573 K. Phase-pure δ-MoN obtained by this means shows a superconducting transition around 5 K.en_US
dc.description.urihttp://dx.doi.org/10.1016/j.jssc.2006.10.020en_US
dc.language.isoenen_US
dc.publisherAcademic Press Inc Elsevier Scienceen_US
dc.rights© 2007 Elsevier Incen_US
dc.subjectnitridesen_US
dc.subjectnanoparticlesen_US
dc.subjectTransition-Metal Nitridesen_US
dc.subjectMolybdenum Nitrideen_US
dc.subjectCrystal-Structureen_US
dc.subjectRouteen_US
dc.subjectThermolysisen_US
dc.subjectDiffractionen_US
dc.subjectPowderen_US
dc.subjectPhaseen_US
dc.subjectMo2nen_US
dc.subjectUreaen_US
dc.titleNanoparticles of superconducting γ-Mo2N and δ-MoNen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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