Please use this identifier to cite or link to this item: https://libjncir.jncasr.ac.in/xmlui/handle/10572/1232
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dc.contributor.authorAnanthavel, S P-
dc.contributor.authorGanguli, B-
dc.contributor.authorChandrashekhar, J-
dc.contributor.authorHegde, M S-
dc.contributor.authorRao, C N R-
dc.date.accessioned2012-12-07T04:28:19Z-
dc.date.available2012-12-07T04:28:19Z-
dc.date.issued1994-01-07-
dc.identifier0009-2614en_US
dc.identifier.citationChemical Physics Letters 217(1-2), 101-104 (1994)en_US
dc.identifier.urihttps://libjncir.jncasr.ac.in/xmlui/10572/1232-
dc.descriptionRestricted Accessen_US
dc.description.abstractElectron states of the benzene...HCl complex have been studied by UV photoelectron spectroscopy. Two vertical ionization energies of the complex at 10.84 and 12.10 eV have been assigned to π C6H6 and nCl orbitals, respectively. While the π C6H6 orbital in the complex is shifted by 1.57 eV to higher binding energy, the nCl MO is shifted by 0.63 eV to lower binding energy with reference to the corresponding free benzene and HCl molecules. Ab initio MO calculations confirm these assignments. The toluene...HCl complex has also been studied. The larger shifts in the π(1.90 eV) and nCl(0.88 eV) orbital energies in the toluene ...HCl complex compared to those of the benzene…HCl complex are consistent with stronger π hydrogen bonding in the case of toluene.en_US
dc.description.urihttp://dx.doi.org/10.1016/0009-2614(93)E1352-Hen_US
dc.language.isoenen_US
dc.publisherElsevier Science BVen_US
dc.rights© 1994 Elsevier Science BVen_US
dc.subjectRotational-Spectrumen_US
dc.subjectMolecular-Beamen_US
dc.subjectDimeren_US
dc.titleElectron states of benzene. ..HCl and toluene. ..HCl hydrogen bonded complexes by ultraviolet photoelectron spectroscopyen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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