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https://libjncir.jncasr.ac.in/xmlui/handle/10572/2146| Title: | 2D coordination polymer composed of 1D {Ni-II(mu-O)(mu-H2O)Ni-II}(n) ferromagnetic chains: Modulation of magnetic properties based on dehydration and rehydration |
| Authors: | Adalikwu, Stephen Adie Chakraborty, Anindita Hazra, Arpan Ghosh, Dibyajyoti Pati, Swapan Kumar Maji, Tapas Kumar |
| Keywords: | Chemistry Crystallography Coordination polymer Magnetism Dehydration-rehydration Guest responsive behavior Density functional theory Crystal-Structure Spin-Crossover |
| Issue Date: | 2016 |
| Publisher: | Pergamon-Elsevier Science Ltd |
| Citation: | Adalikwu, S. A.; Chakraborty, A.; Hazra, A.; Ghosh, D.; Pati, S. K.; Maji, T. K., 2D coordination polymer composed of 1D {Ni-II(mu-O)(mu-H2O)Ni-II}(n) ferromagnetic chains: Modulation of magnetic properties based on dehydration and rehydration. Polyhedron 2016, 115, 276-281 http://dx.doi.org/10.1016/j.poly.2016.05.011 Polyhedron 115 |
| Abstract: | Synthesis, single-crystal structure and magnetic properties of a 2D coordination compound [Ni(1,3-ADA) (H2O)](n) (1) is reported which exhibits tunable magnetic behavior based on dehydration-rehydration. 1 shows ferromagnetic (FM) interaction between Ni-II ions. Combined detailed experimental and theoretical studies reveal that FM interaction arises due to "orthogonal" magnetic orbitals, which become distorted in desolvated state and suppress the FM interaction. (C) 2016 Elsevier Ltd. All rights reserved. |
| Description: | Restricted Access |
| URI: | https://libjncir.jncasr.ac.in/xmlui/10572/2146 |
| ISSN: | 0277-5387 |
| Appears in Collections: | Research Articles (Swapan Kumar Pati) Research Articles (Tapas Kumar Maji) |
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