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https://libjncir.jncasr.ac.in/xmlui/handle/10572/2356| Title: | Few-Layer Borocarbonitride Nanosheets: Platinum-Free Catalyst for the Oxygen Reduction Reaction |
| Authors: | Moses, Kota Kiran, Vankayala Sampath, S. Rao, C. N. R. |
| Keywords: | Chemistry Doping Layered Compounds Nanostructures Nitrides Reduction Metal-Free Electrocatalysts Carbon Nanotube Arrays Doped Graphene Fuel-Cells Nitrogen Performance Sulfur Boron Nanoparticles Phosphorus |
| Issue Date: | 2014 |
| Publisher: | Wiley-V C H Verlag Gmbh |
| Citation: | Moses, K; Kiran, V; Sampath, S; Rao, CNR, Few-Layer Borocarbonitride Nanosheets: Platinum-Free Catalyst for the Oxygen Reduction Reaction. Chemistry-An Asian Journal 2014, 9 (3) 838-843, http://dx.doi.org/10.1002/asia.201301471 Chemistry-An Asian Journal 9 3 |
| Abstract: | The present study demonstrates the use of few-layer borocarbonitride nanosheets synthesized by a simple method as non-platinum cathode catalysts for the oxygen reduction reaction (ORR) in alkaline medium. Composition-dependent ORR activity is observed and the best performance was found when the composition was carbon-rich. Mechanistic aspects reveal that ORR follows the 4e(-) pathway with kinetic parameters comparable to those of the commercial Pt/C catalyst. Excellent methanol tolerance is observed with the BCN nanosheets unlike with Pt/C. |
| Description: | Restricted Access |
| URI: | https://libjncir.jncasr.ac.in/xmlui/10572/2356 |
| ISSN: | 1861-4728 |
| Appears in Collections: | Research Papers (Prof. C.N.R. Rao) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 98.pdf Restricted Access | 443.05 kB | Adobe PDF | View/Open Request a copy |
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