A hexanuclear Cu(I) cluster supported by cuprophilic interaction: effects of aromatics on luminescence properties

Please use this identifier to cite or link to this item: https://libjncir.jncasr.ac.in/xmlui/handle/10572/2427

Title:	A hexanuclear Cu(I) cluster supported by cuprophilic interaction: effects of aromatics on luminescence properties
Authors:	Chakraborty, Anindita Ramachandran, Krishna Kumar Yamijala, Sharma S. R. K. C. Pati, Swapan Kumar Maji, Tapas Kumar
Keywords:	Chemistry Ray Crystal-Structures Copper(I) Selenolate Phosphine-Ligands Complexes Coordination Carboxylate Reactivity Discrete Polymers Sensors
Issue Date:	2014
Publisher:	Royal Society of Chemistry
Citation:	Chakraborty, A; Ramachandran, KK; Yamijala, SSRKC; Pati, SK; Maji, TK, A hexanuclear Cu(I) cluster supported by cuprophilic interaction: effects of aromatics on luminescence properties. RSC Advances 2014, 4 (66) 35167-35170, http://dx.doi.org/10.1039/c4ra06183g RSC Advances 4 66
Abstract:	A hexanuclear Cu(I) cluster {Cu-3(L)(2)}(2) (1) based on a novel tripodal linker (L) has been synthesized. 1 shows intense emission (lambda(max) 560 nm) with lifetime <tau > = 224 ms and quantum yield = 27.6%. The emission is highly sensitive towards different electron rich and electron deficient aromatics. DFT calculations were performed to understand the origin of emission and sensing properties.
Description:	Restricted Access
URI:	https://libjncir.jncasr.ac.in/xmlui/10572/2427
ISSN:	2046-2069
Appears in Collections:	Research Articles (Swapan Kumar Pati) Research Articles (Tapas Kumar Maji)

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